4-硝基重氮苯四氟硼酸盐合成路线 （共 247 条）
反应条件
nickel dichloride; zinc in tetrahydrofuran Reduction;
参考文献
Journal of Chemical Research - Part S, , # 12 p. 714 - 715
反应条件
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; N,N-dimethyl-formamide byproducts: 4-NO2OC6H4CH2CH(SCN)CONHCH2NHCOCHCH2; addn. of 4-NO2C6H4N2BF4 (1.1 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and NH4SCN (1.1 equiv.) in H2O-DMF (1:3) for 30 min; evolution of gas at 10-15°C for 45 min;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
反应条件
Cu(BF4)2 in water; acetone addn. of NO2C6H4N2BF4 to 1,4-bis(acryloyloxy)butane, Cu(BF4)2 and NH4SCNin aq. acetone (1:2) for 45-60 min; cooling at -10 - -5°C for 2 h; evolution of N2, treatment of residual with Et2O, extn., washing with water, drying with MgSO4, removal of ether, chromy.;
参考文献
Gorbovoi; Baranovskii; Koval'skii; Grishchuk
Russian Journal of General Chemistry, 2002 , vol. 72, # 8 p. 1230 - 1232
反应条件
hydrogenchloride in water T=50°C; KineticsProduct distribution; Further Variations:acidity, solvent composition;
参考文献
Pazo-Llorente, Roman; Maskill, Howard; Bravo-Diaz, Carlos; Gonzalez-Romero, Elisa
European Journal of Organic Chemistry, 2006 , # 9 p. 2201 - 2209
反应条件
sodium nitrite in methanol T=0°C; 0.0333333 h; Further byproducts given;
参考文献
Tetrahedron Letters, , vol. 23, # 49 p. 5191 - 5194
反应条件
sodium nitrite in water T=25 - 29.9°C; Kinetics;
参考文献
Bagal,L.I. et al.
Zhurnal Organicheskoi Khimii, 1969 , vol. 5, # 10 p. 1820 - 1828,1767 - 1774
参考文献
Starkey
Journal of the American Chemical Society, 1937 , vol. 59, p. 1479
Organic Syntheses, Col. Vol. II <1943> 225, 226
反应条件
1: 55 percent / tetrahydrothiophene 1,1-dioxide / 2 h / 80 °C 2: 5 h / 180 °C View Scheme
参考文献
Abramovitch, Rudolph A.; Alvernhe, Gerard; Bartnik, Romuald; Dassanayake, Nissanke L.; Inbasekaran, Mutiah N.; Kato, Shiego
Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4558 - 4565
反应条件
1: Py 2: H2 / PtO2 / ethanol; diethyl ether 3: aq. H2SO4, NaNO2 4: Py*HCl / 5 h / 220 °C View Scheme
参考文献
Musso,H.; Pietsch,H.
Chemische Berichte, 1967 , vol. 100, p. 2854 - 2869
反应条件
tetrabutyl-ammonium chloride in acetonitrile
参考文献
Stovpovoi, P. A.; Bagal, I. L.; El'tsov, A. V.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 8 p. 1859 - 1872,1642 - 1654
