4-硝基重氮苯四氟硼酸盐合成路线 （共 247 条）
反应条件
4-NO2C6H4CH2CH(SCN)CONHCH2NHCOCHCH2; Cu(BF4)2*6H2O in water; N,N-dimethyl-formamide byproducts: NO2C6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4NO2; addn. of 4-NO2C6H4N2BF4 to 4-NO2C6H4CH2CH(SCN)CONHCH2NHCOCHCH2, Cu(BF4)2*6H2O and KSCN in H2O-DMF (1:3) for 20 min; evolution of gas at 15-20°C for 45 min;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
反应条件
Cu(BF4)2 in water; acetone addn. of NO2C6H4N2BF4 to soln. of 1,4-bis(acryloyloxy)butane, Cu(BF4)2 and KSCN in aq. acetone (1:2) for 45-60 min; cooling at -10 - -5°Cfor 2 h; evolution of N2; treatment of residual with Et2O, extn., washing with water, drying with MgSO4, removal of ether, chromy.;
参考文献
Gorbovoi; Baranovskii; Koval'skii; Grishchuk
Russian Journal of General Chemistry, 2002 , vol. 72, # 8 p. 1230 - 1232
反应条件
1 Pd/C in methanol T=50°C; Suzuki-Miyaura reaction; 0.166667 h; Inert atmosphere;
参考文献
Bonin, Helene; Delbrayelle, Dominique; Demonchaux, Patrice; Gras, Emmanuel
Chemical Communications, 2010 , vol. 46, # 15 p. 2677 - 2679
反应条件
KOH adsorbed on neutral alumina in neat (no solvent) 0.25 h; Milling;
参考文献
Mukherjee, Nirmalya; Chatterjee, Tanmay; Ranu, Brindaban C.
Journal of Organic Chemistry, 2013 , vol. 78, # 21 p. 11110 - 11114
反应条件
in water T=40°C; 4 h;
参考文献
Singh, Abhilash S.; Shendage, Suresh S.; Nagarkar, Jayashree M.
Tetrahedron Letters, 2013 , vol. 54, # 47 p. 6319 - 6323
反应条件
in dimethyl sulfoxide T=25°C; 0.25 h;
参考文献
Petrillo, Giovanni; Novi, Marino; Garbarino, Giacomo; Dell'Erba, Carlo
Tetrahedron, 1986 , vol. 42, # 14 p. 4007 - 4016
反应条件
palladium diacetate in acetonitrile 2 h; Ambient temperature;
参考文献
Kikukawa, Kiyoshi; Kono, Kiyoshi; Wada, Fumio; Matsuda, Tsutomu
Journal of Organic Chemistry, 1983 , vol. 48, # 8 p. 1333 - 1336
反应条件
2-iodo-propane; copper in dimethyl sulfoxide 3 h; Ambient temperature; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Journal of Chemical Research, Miniprint, , # 4 p. 876 - 890
反应条件
copper in dimethyl sulfoxide T=20°C; 1 h; other catalyst, other time; Rate constantMechanismProduct distribution;
参考文献
Journal of Chemical Research, Miniprint, , # 4 p. 876 - 890
反应条件
water; sodium acetate in acetonitrile T=0°C; 1.16667 h; Inert atmosphere;
参考文献
Basavanag, Unnamatla M. V.; Dos Santos, Aurelie; El Kaim, Laurent; Gamez-Montano, Rocio; Grimaud, Laurence
Angewandte Chemie - International Edition, 2013 , vol. 52, # 28 p. 7194 - 7197
Angew. Chem., 2013 , vol. 125, # 28 p. 7335 - 7338,4
