1.1: hydroxylamine hydrochloride; sodium hydroxide; water / ethanol / 4 h / 5 °C 2.1: acetic anhydride / 2 h / 110 °C 3.1: magnesium / tetrahydrofuran / 0.5 h / 40 °C 3.2: 1 h / 40 °C View Scheme
参考文献
Rao, A. V. Rama; Rao, Ramakrishna; Yadav; Khagga, Mukkanti
Synthetic Communications, 2013 , vol. 43, # 12 p. 1661 - 1667
1: With potassium carbonate Horner-Wadsworth-Emmons olefination; 6 h; Neat (no solvent)high-speed ball milling; 2: With Oxonereg; 12 h; Neat (no solvent)high-speed ball milling; optical yield given as percent dediastereoselective reaction;
参考文献
Shearouse, William C.; Korte, Chelsea M.; Mack, James
Green Chemistry, 2011 , vol. 13, # 3 p. 598 - 601
4-hydroxyacetophenone monooxygenase from P. fluorescens ACB; oxygen; NADPH in phosphate buffer T=30°C; Baeyer-Villiger oxidation; pH=8.0; 1 h; Enzyme kinetics;
参考文献
Moonen, Marielle J. H.; Westphal, Adrie H.; Rietjens, Ivonne M. C. M.; Van Berkel, Willem J. H.
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 7-8 p. 1027 - 1034
4-hydroxyacetophenone monooxygenase from P. fluorescens ACB; oxygen; NADPH in phosphate buffer T=30°C; Baeyer-Villiger oxidation; pH=8.0; 1 h; Enzyme kinetics;
参考文献
Moonen, Marielle J. H.; Westphal, Adrie H.; Rietjens, Ivonne M. C. M.; Van Berkel, Willem J. H.
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 7-8 p. 1027 - 1034
