in methanol

in methanol byproducts: NH4Br; under N2, react. of equimolar amts. of educts in methanol; filtered, evapd., extd. with CH2Cl2, evapd. in vac., dried in vac. at 373 K for 1 h;

in N,N-dimethyl-formamide 25.0+/-0.2°C, presence of Et4NClO4; thermodynamics and stepwise formation constants of cadmium thiocyanato complexes determination; not isolated; calorimetric titrations, Raman spectroscopy;