1-(3-丁烯-1-基)-2-甲基苯合成路线 (共 9 条)
反应条件
1: 2-propenylmagnesium bromide With manganese (II) chloride in tetrahydrofuran Metallation; 2: α,α,α',α'-tetrabromo-o-xylene in tetrahydrofuran T=0°C; Substitution; 2.5 h; 3: With water Substitution;
参考文献
Kakiya; Shinokubo; Oshima
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 9 p. 2139 - 2147
反应条件
in tetrahydrofuran; diethyl ether T=0°C; 2 h; Inert atmosphere;
参考文献
Bigi, Marinus A.; White, M. Christina
Journal of the American Chemical Society, 2013 , vol. 135, # 21 p. 7831 - 7834
反应条件
mercury(II) tetrafluoroborate in 1,4-dioxane; water T=20°C; 72 h;
参考文献
Julia,M.; Fourneron,J.-D.
Bulletin de la Societe Chimique de France, 1975 , p. 770 - 774
参考文献
Biswas, Soumik; Weix, Daniel J.
Journal of the American Chemical Society, 2013 , vol. 135, # 43 p. 16192 - 16197
反应条件
C54H80Cl2Fe2N2O4 in diethyl ether Inert atmosphere;
参考文献
Qian, Xin; Dawe, Louise N.; Kozak, Christopher M.
Dalton Transactions, 2011 , vol. 40, # 4 p. 933 - 943
反应条件
1: tetrahydrofuran / 20 °C 2: 60 °C View Scheme
参考文献
Biswas, Soumik; Weix, Daniel J.
Journal of the American Chemical Society, 2013 , vol. 135, # 43 p. 16192 - 16197
反应条件
(i) LiAlH4, (ii) (acetylation), (iii) (pyrolysis); Multistep reaction;
参考文献
Gutsche,C.D. et al.
Tetrahedron, 1962 , vol. 18, p. 617 - 627
参考文献
Yoshino, Hideaki; Toda, Narihiro; Kobata, Masami; Ukai, Katsumi; Oshima, Koichiro; Utimoto, Kiitiro; Matsubara, Seijiro
Chemistry - A European Journal, 2006 , vol. 12, # 3 p. 721 - 726
反应条件
hydrogen; palladium on activated charcoal in ethyl acetate
P=760 Torr;
参考文献
Julia,M.; Fourneron,J.-D.
Bulletin de la Societe Chimique de France, 1975 , p. 770 - 774