4-甲基偶氮苯四氟硼酸盐合成路线 （共 216 条）
反应条件
N,N-methylenediacrylamide; Cu(BF4)2*6H2O in water; dimethyl sulfoxide byproducts: MeC6H4CH2CH(SCN)CONHCH2NHCOCH(SCN)CH2C6H4Me; addn. of 4-MeC6H4N2BF4 (2.2 equiv.) to N,N-methylenediacrylamide (1 equiv.), Cu(BF4)2*6H2O (0.1 equiv.) and KSCN (1.1 equiv.) in H2O-DMSO (1:4) for 45 min; evolution of gas at 10-15°C for 1 h;
参考文献
Grishchuk; Baranovskii; Gorbovoi; Ganushchak
Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 957 - 960
反应条件
Cu(BF4)2 in water; acetone addn. of CH3C6H4N2BF4 to 1,4-bis(acryloyloxy)butane, Cu(BF4)2 and KSCN in aq. acetone (1:2) for 45-60 min; cooling at -10 - -5°C for 2 h; evolution of N2, treatment of residual with Et2O, extn., washing with water, drying with MgSO4, removal of ether, chromy.;
参考文献
Gorbovoi; Baranovskii; Koval'skii; Grishchuk
Russian Journal of General Chemistry, 2002 , vol. 72, # 8 p. 1230 - 1232
反应条件
1: (E)-trimethyllt;2-(4-methylphenyl)ethenylgt;silane With boron trichloride in dichloromethane T=0°C; Substitution; 2 h; 2: 4-toluenediazonium tetrafluoroborate With palladium diacetate in 1,4-dioxane T=20°C; Substitution; 24 h; Further stages.;
参考文献
Babudri, Francesco; Farinola, Gianluca M.; Naso, Francesco; Panessa, Daniela
Journal of Organic Chemistry, 2000 , vol. 65, # 5 p. 1554 - 1557
反应条件
palladium diacetate in methanol T=60°C; 1 h;
参考文献
Sengupta, Saumitra; Bhattacharyya, Sanchita; Sadhukhan, Subir Kumar
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 2 p. 275 - 277
反应条件
di-μ-chlorobis [5-hydroxy-2-[1-(hydroxyimino)ethyl]phenyl]palladium(II) dimer in methanol; water T=60°C; Heck Reaction; 2.5 h; Catalytic behavior; SolventTemperatureTime;
参考文献
Salabert, Jordi; Sebastian, Rosa Maria; Vallribera, Adelina; Civicos, Jose Francisco; Najera, Carmen
Tetrahedron, 2013 , vol. 69, # 12 p. 2655 - 2659
参考文献
Nazaretyan, V. P.; Kamenskaya, O. I.
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 686
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 690
C.A., 1976 , vol. 84, p. 164331
Full Text Show Details
Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.4, page 152 - 186
反应条件
byproducts: N2; equimolar mixture, 60-80°C;
参考文献
Nazaretyan, V. P.; Kamenskaya, O. I.
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 686
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 690
C.A., 1976 , vol. 84, p. 164331
Full Text Show Details
Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120
反应条件
1,6,11-triazacyclopentadeca-3,8,12-triene Pd in ethanol T=20°C; Heck reaction; 0.75 h;
参考文献
Masllorens, Judit; Moreno-Manas, Marcial; Pla-Quintana, Anna; Roglans, Anna
Organic Letters, 2003 , vol. 5, # 9 p. 1559 - 1561
反应条件
tetraethylammonium bromide in dichloromethane; acetonitrile T=20°C; Irradiationalso without CH2Cl2; Product distributionQuantum yield;
参考文献
Becker, H.G.O.; Israel, G.; Oertel, Ulrike; Vetter, H.-U.
Journal fuer Praktische Chemie (Leipzig), 1985 , vol. 327, # 3 p. 399 - 410
反应条件
in dichloromethane; acetonitrile Irradiationalso with crown ethers, different conc. of the crown ether; Quantum yieldProduct distribution;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 326, # 1 p. 92 - 100
