4-甲氧苯重氮四氟硼酸盐合成路线 （共 231 条）
反应条件
1: (trifluoromethyl)-trimethylsilane With copper(I) isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: 4-methoxybenzenediazonium tetrafluoroborate in acetonitrile T=20°C; Sandmeyer Reaction; 16 h; Inert atmosphere; Reagent/catalystSolvent;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 7972 - 7975
Angew. Chem., 2013 , vol. 125, # 31 p. 8130 - 8133
反应条件
water; sodium acetate in acetonitrile T=0°C; 1.16667 h; Inert atmosphere;
参考文献
Basavanag, Unnamatla M. V.; Dos Santos, Aurelie; El Kaim, Laurent; Gamez-Montano, Rocio; Grimaud, Laurence
Angewandte Chemie - International Edition, 2013 , vol. 52, # 28 p. 7194 - 7197
Angew. Chem., 2013 , vol. 125, # 28 p. 7335 - 7338,4
反应条件
SIDip*HCl; palladium diacetate in tetrahydrofuran T=20°C; 1 h;
参考文献
Ma, Yudao; Song, Chun; Jiang, Wei; Xue, Guoping; Cannon, John F.; Wang, Xiaomei; Andrus, Merritt B.
Organic Letters, 2003 , vol. 5, # 24 p. 4635 - 4638
反应条件
1: tBuCH2CH2B(H)NiPr2; 4-methoxybenzenediazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; SolventReagent/catalystConcentration;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 55-56 ;
反应条件
1: With triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in 1,4-dioxane T=80°C; 18 h; 2: 4-methoxybenzenediazonium tetrafluoroborate; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in 1,4-dioxane T=80°C; 18 h;
参考文献
Commonwealth Scientific and Industrial Research Organisation
Patent: US6680401 B1, 2004 ;
Location in patent: Page column 65 ;
反应条件
palladium diacetate; SIDip*HCl in tetrahydrofuran T=20°C; Mizoroki-Heck coupling; 3.5 h;
参考文献
Andrus, Merritt B.; Song, Chun; Zhang, Jiuqing
Organic Letters, 2002 , vol. 4, # 12 p. 2079 - 2082
反应条件
palladium diacetate in methanol T=60°C; 1 h;
参考文献
Sengupta, Saumitra; Bhattacharyya, Sanchita; Sadhukhan, Subir Kumar
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 2 p. 275 - 277
反应条件
iron(II) sulfate in water; dimethyl sulfoxide 0.166667 h;
参考文献
Heinrich, Markus R.; Blank, Olga; Ullrich, Daniela; Kirschstein, Marcel
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9609 - 9616
反应条件
iron(II) sulfate in water; dimethyl sulfoxide 0.166667 h;
参考文献
Heinrich, Markus R.; Blank, Olga; Ullrich, Daniela; Kirschstein, Marcel
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9609 - 9616
反应条件
palladium diacetate; SIDip*HCl in 1,4-dioxane T=100°C; P=760 Torr; 5 h;
参考文献
Andrus, Merritt B.; Ma, Yudao; Zang, Yunfu; Song, Chun
Tetrahedron Letters, 2002 , vol. 43, # 50 p. 9137 - 9140
