1,1,1,3,3-五氟丙烷合成路线 （共 90 条）
反应条件
chlorine T=2 - 3°C; 3 h; Irradiation;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2006/69105 A1, 2006 ;
Location in patent: Page/Page column 12 ;
反应条件
chlorine T=20°C; 0.00472222 h; Irradiation;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2006/69105 A1, 2006 ;
Location in patent: Page/Page column 13 ;
反应条件
chlorine T=20°C; 0.00305556 - 0.00472222 h; Irradiation; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2006/69105 A1, 2006 ;
Location in patent: Page/Page column 13 ;
反应条件
hydrogen fluoride; SbF5 T=120 - 121°C; P=9551.8 - 29721.1 Torr; 3.5 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2007/118003 A1, 2007 ;
Location in patent: Page/Page column 4-5 ;
反应条件
potassium hydroxide in anhydrous butyl ether
参考文献
Honeywell International Inc.
Patent: US2005/245773 A1, 2005 ;
Location in patent: Page/Page column 3 ;
反应条件
hydrogen fluoride; SbF5
T=120 - 121°C; P=9551.8 - 29721.1 Torr; 3.5 h; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US2007/118003 A1, 2007 ;
Location in patent: Page/Page column 4-5 ;
反应条件
10percent CsCl/90percent MgF2 treated at 480 C
T=470°C; P=3087.28 Torr; Gas phase; Product distribution / selectivity;
参考文献
Honeywell International Inc.
Patent: US7829748 B1, 2010 ;
Location in patent: Page/Page column 6-7 ;
反应条件
n-BuLi in diethyl ether
under N2 atm. soln. CF3CH2CF2H in Et2O at -10°C was treated with n-BuLi, after 10 min Ph3GeBr in Et2O was added and stirred at 0°Covernight and warmed to room temp.; hexane was added, soln. was filtered, concd. in vacuo, and chromed. on silica; elem. anal.;
参考文献
Brisdon, Alan K.; Crossley, Ian R.; Pritchard, Robin G.; Sadiq, Ghazala; Warren, John E.
Organometallics, 2003 , vol. 22, # 26 p. 5534 - 5542
反应条件
n-BuLi in diethyl ether
under N2 atm. soln. CF3CH2CF2H in Et2O at -10°C was treated with n-BuLi, after 10 min Ph3PbCl in Et2O was added and stirred at 0°Covernight and warmed to room temp.; hexane was added, soln. was filtered, concd. in vacuo, and chromed. on silica; elem. anal.;
参考文献
Brisdon, Alan K.; Crossley, Ian R.; Pritchard, Robin G.; Sadiq, Ghazala; Warren, John E.
Organometallics, 2003 , vol. 22, # 26 p. 5534 - 5542
反应条件
1: 1,1,1,3,3-pentafluoropropane With n-butyllithium in diethyl ether; hexane
T=-10°C;
2: benzoyl chloride in diethyl ether; hexane
参考文献
Brisdon, Alan K.; Crossley, Ian R.
Chemical Communications, 2002 , # 20 p. 2420 - 2421
