烯丙基 3-O-苄基-alpha-L-吡喃鼠李糖苷合成路线 （共 2 条）
反应条件
1: allyl α-L-rhamnopyranoside With di(n-butyl)tin oxide in toluene
Heating;
2: benzyl bromide With cesium fluoride in N,N-dimethyl-formamide
参考文献
Fuerstner, Alois; Jeanjean, Fabien; Razon, Patrick; Wirtz, Conny; Mynott, Richard
Chemistry - A European Journal, 2003 , vol. 9, # 1 p. 307 - 319
反应条件
1.1: acetyl chloride / 0.33 h / 0 °C
1.2: 3 h / |Reflux
2.1: di(n-butyl)tin oxide / toluene / 3.5 h / |Dean-Stark; |Reflux
2.2: 12 h / 20 °C
View Scheme
参考文献
Pogosyan, Amayak; Gottwald, Andreas; Michalik, Dirk; Endress, Hans-Ulrich; Vogel, Christian
Carbohydrate Research, 2013 , vol. 380, p. 9 - 15
