4,4,4-三氟-1-碘丁烷合成路线 （共 10 条）
反应条件
phosphoric acid; potassium iodide T=120°C;
参考文献
Walborsky et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 3637,3639
反应条件
15-crown-5; cesium fluoride in ethylene glycol dimethyl ether T=-18 - 20°C; 1 h;
参考文献
Tyrra, Wieland; Naumann, Dieter; Quadt, Silke; Buslei, Sigrid; Yagupolskii, Yurii L.; Kremlev, Mikhail M.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 813 - 817
反应条件
1: tetrahydrofuran-2-one With potassium hydroxide in water T=50 - 140°C; P=150.015 - 760.051 Torr; 2: 1,1,1-trifluoro-4-iodobutane in water T=75 - 140°C; 7 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 4 ;
反应条件
potassium hydroxide; water in gamma-butyro-lactone T=90 - 100°C; 18.8 h; Product distribution / selectivity;
参考文献
Tosoh Corporation; Tosoh F-Tech Inc.
Patent: JP2005/187423 A, 2005 ;
Location in patent: Page/Page column 6 ;
反应条件
sodium hydroxide in water T=90°C; 36 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 5 ;
反应条件
tetrahydrofuran-2-one in acetic acid T=75 - 140°C; 7 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 4 ;
反应条件
1: tetrahydrofuran-2-one With potassium hydroxide in water T=50 - 140°C; P=150.015 - 760.051 Torr; 2: 1,1,1-trifluoro-4-iodobutane in water T=75 - 140°C; 7 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 4 ;
反应条件
potassium hydroxide; water in gamma-butyro-lactone T=90 - 100°C; 18.8 h; Product distribution / selectivity;
参考文献
Tosoh Corporation; Tosoh F-Tech Inc.
Patent: JP2005/187423 A, 2005 ;
Location in patent: Page/Page column 6 ;
反应条件
sodium hydroxide in water T=90°C; 36 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 5 ;
反应条件
1: With platinum
T=-178.16°C; P=2E-10 Torr;
2: With hydrogen
T=-178.16 - 226.84°C; P=2E-10 Torr; Activation energy;
参考文献
Ye, Pingping; Gellman, Andrew J.
Journal of the American Chemical Society, 2008 , vol. 130, # 26 p. 8518 - 8526
