(2E)-3,7-二甲基-2,6-辛二烯酸合成路线 （共 18 条）
反应条件
hydrogen; sodium methylate; Rh-6 in methanol T=0°C; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 45, # 18 p. 3698 - 3703
反应条件
hydrogen; sodium methylate; Rh-6 in methanol T=0°C; Product distribution;
参考文献
Valentine, Donald; Sun, Ruen C.; Toth, Katherine
Journal of Organic Chemistry, 1980 , vol. 45, # 18 p. 3703 - 3707
反应条件
ammonium formate; palladium on activated charcoal in methanol T=70°C; 3 h;
参考文献
Ranu, Brindaban C.; Sarkar, Arunkanti
Tetrahedron Letters, 1994 , vol. 35, # 46 p. 8649 - 8650
反应条件
sodium chlorite; sodium dihydrogenphosphate in water; acetone
T=20°C; 7 h;
参考文献
Dong, Hong-Bo; Yang, Ming-Yan; Jiang, Jia-Zheng; Wang, Ming-An
Journal of Asian Natural Products Research, 2013 , vol. 15, # 8 p. 880 - 884
反应条件
1: Me2C=CHCH2CH2MgBr With zinc dibromide in diethyl ether
T=25°C;
2: (Z)-3-iodo-3-methylpropenoic acid With dichloro bis(acetonitrile) palladium(II) in tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide
T=25°C; 12 h;
参考文献
Abarbri, Mohamed; Thibonnet, Jerome; Parrain, Jean-Luc; Duchene, Alain
Synthesis, 2002 , # 4 p. 543 - 551
反应条件
formaldehyd; oxygen; bismuth(III)oxide; 2.5 weight platinum on activated charcoal in water
T=20 - 45°C; 4.5 h; Conversion of starting material;
参考文献
Jacquot, Roland
Patent: US2006/100459 A1, 2006 ;
Location in patent: Page/Page column 4; 5 ;
反应条件
Pd(OAc)2*PPh3; triethylammonium formate in 1,4-dioxane
4.5 h; Heating;
参考文献
Otera, Junzo; Yano, Toru; Kawabata, Atsuya; Nozaki, Hitosi
Tetrahedron Letters, 1986 , vol. 27, # 21 p. 2383 - 2386
反应条件
sodium hydroxide; silver nitrate in methanol; water
T=55 - 56°C; 0.75 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Valentine Jr.; Johnson; Priester; et al.
Journal of Organic Chemistry, 1980 , vol. 45, # 18 p. 3698 - 3703
反应条件
1: 90 percent / SCNBu2Sn-O-SnBu2OH / 43 h / Heating
2: 90 percent / Pd(OAc)2-Ph3P/Et3N-HCOOH / dioxane / 4.5 h / Heating
View Scheme
参考文献
Otera, Junzo; Yano, Toru; Kawabata, Atsuya; Nozaki, Hitosi
Tetrahedron Letters, 1986 , vol. 27, # 21 p. 2383 - 2386
反应条件
silver(l) oxide in water
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Valentine Jr.; Johnson; Priester; et al.
Journal of Organic Chemistry, 1980 , vol. 45, # 18 p. 3698 - 3703
