2-甲氧基-4-(4,4,5,5-四甲基-1,3,2-三氧杂硼戊环-2-基)苯胺合成路线 （共 6 条）
反应条件
trifluoroacetic acid in dichloromethane T=5 - 20°C; 2 h;
参考文献
US2005/20619 A1, ;
Page 40-41 ;
US 20050020619 A1
反应条件
1: benzhydryliden-(4-bromo-2-methoxyphenyl)-amine With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=-85°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol With sodium hydroxide; sulfuric acid more than 3 stages;
参考文献
US2008/269523 A1, ;
Page/Page column 6 ;
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate in dimethyl sulfoxide T=80°C; 2 h;
参考文献
Bioorganic and Medicinal Chemistry Letters, , vol. 21, # 3 p. 966 - 970
反应条件
1: tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere; |Glovebox 2: bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 3,4,7,8-tetra-methyl-1,10-phenanthroline / tetrahydrofuran / 16 h / 80 °C / |Inert atmosphere; |Glovebox 3: methanol / tetrahydrofuran / 20 °C / |Inert atmosphere; |Glovebox View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 49 p. 12915 - 12919
Angew. Chem., , vol. 125, # 49 p. 13153 - 13157,5
反应条件
1: bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 3,4,7,8-tetra-methyl-1,10-phenanthroline / tetrahydrofuran / 16 h / 80 °C / |Inert atmosphere; |Glovebox 2: methanol / tetrahydrofuran / 20 °C / |Inert atmosphere; |Glovebox View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 49 p. 12915 - 12919
Angew. Chem., , vol. 125, # 49 p. 13153 - 13157,5
参考文献
Kressierer, Christoph J.; Lehnemann, Bernd; Jung, Jorg
Patent: US2008/269523 A1, 2008 ;
Location in patent: Page/Page column 6-7 ;
