2-(苯氧基甲基)四氢呋喃合成路线 （共 10 条）
反应条件
1: 98 percent / pyridine / tetrahydrofuran / 2 h / 0 °C
2: 67 percent / Ph3P, DEAD / tetrahydrofuran / 3 h
3: 67 percent / NaBH4, Cu(acac)2 / ethanol / 1.5 h
4: 94 percent / aq. NaOH / ethanol / 2 h / Heating
5: 1.) NOBF4 / 2.) tetrathiafulvalene / 1.) CH2Cl2, 0 deg C, 2.) aq. acetone, 30 min
View Scheme
参考文献
Murphy, John A.; Rasheed, Faiza; Roome, Stephen J.; Lewis, Norman
Chemical Communications, 1996 , # 6 p. 737 - 738
反应条件
1: 67 percent / Ph3P, DEAD / tetrahydrofuran / 3 h
2: 67 percent / NaBH4, Cu(acac)2 / ethanol / 1.5 h
3: 94 percent / aq. NaOH / ethanol / 2 h / Heating
4: 1.) NOBF4 / 2.) tetrathiafulvalene / 1.) CH2Cl2, 0 deg C, 2.) aq. acetone, 30 min
View Scheme
参考文献
Murphy, John A.; Rasheed, Faiza; Roome, Stephen J.; Lewis, Norman
Chemical Communications, 1996 , # 6 p. 737 - 738
反应条件
1: 94 percent / aq. NaOH / ethanol / 2 h / Heating
2: 1.) NOBF4 / 2.) tetrathiafulvalene / 1.) CH2Cl2, 0 deg C, 2.) aq. acetone, 30 min
View Scheme
参考文献
Murphy, John A.; Rasheed, Faiza; Roome, Stephen J.; Lewis, Norman
Chemical Communications, 1996 , # 6 p. 737 - 738
反应条件
1: 67 percent / NaBH4, Cu(acac)2 / ethanol / 1.5 h
2: 94 percent / aq. NaOH / ethanol / 2 h / Heating
3: 1.) NOBF4 / 2.) tetrathiafulvalene / 1.) CH2Cl2, 0 deg C, 2.) aq. acetone, 30 min
View Scheme
参考文献
Murphy, John A.; Rasheed, Faiza; Roome, Stephen J.; Lewis, Norman
Chemical Communications, 1996 , # 6 p. 737 - 738
反应条件
NOBF4; tetrathiafulvalene
1.) CH2Cl2, 0 deg C, 2.) aq. acetone, 30 min; Yield given. Multistep reaction;
参考文献
Murphy, John A.; Rasheed, Faiza; Roome, Stephen J.; Lewis, Norman
Chemical Communications, 1996 , # 6 p. 737 - 738
反应条件
nickel
T=85°C; P=42659.5 Torr; Hydrogenation;
参考文献
Paul; Normant
Bulletin de la Societe Chimique de France, 1938 , vol. <5> 5, p. 1148,1151
反应条件
1: ethanol
2: Raney nickel / 85 °C / 42659.5 Torr / Hydrogenation
View Scheme
参考文献
Paul; Normant
Bulletin de la Societe Chimique de France, 1938 , vol. <5> 5, p. 1148,1151
反应条件
1: ethanol
2: Raney nickel / 85 °C / 42659.5 Torr / Hydrogenation
View Scheme
参考文献
Paul; Normant
Bulletin de la Societe Chimique de France, 1938 , vol. <5> 5, p. 1148,1151
反应条件
potassium carbonate; butanone
参考文献
Paul; Normant
Bulletin de la Societe Chimique de France, 1945 , vol. <5> 12, p. 388,393
参考文献
Paul; Normant
Bulletin de la Societe Chimique de France, 1938 , vol. <5> 5, p. 1148,1151
