in neat (no solvent) other Radiation; COS was flowed through a radio frequence plasma zone at 0.06 - 0.30 Torr, power 5 - 25 W; further products; not isolated, detected by MAS and emission spectroscopy;
参考文献
Bezuk, Steve J.; Miller, Larry L.; Platzner, I.
Journal of Physical Chemistry, 1983 , vol. 87, # 1 p. 131 - 136
methane in solid matrix byproducts: CH3SH, H2CS; Irradiation (UV/VIS); photolysis of solid matrix CH4:OCS=100:1 using unfiltered emission of amedium pressure Hg arc at 20 K for 2 h; with or without annealing matrix to 40 K for 30 min; with or without irradiation for a total of 4 h; mechanism discussed;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
acetylene in solid matrix byproducts: H2CCS, HCCSH, HCCHS; Irradiation (UV/VIS); photolysis of solid matrix Ar:C2H2:OCS=100:1:1 using unfiltered emission from Cd-arc for 240 min at 20 K; mechanism discussed;; not isolated; detn. in solid matrix by IR spectroscopy;;
参考文献
Hawkins, Michael; Almond, Matthew; Downs, Anthony J.
Journal of Physical Chemistry, 1985 , vol. 89, # 15 p. 3326 - 3334
