in tetrahydrofuran
Kinetics; complete thermolysis of cis-{bis(dicyclohexylphophino)ethane}hydridoneopentylplatinum(II) in THF contg. bis(dicyclohexylphosphino)ethane;
参考文献
Hackett, Marifaith; Ibers, James A.; Whitesides, George M.
Journal of the American Chemical Society, 1988 , vol. 110, # 5 p. 1436 - 1448
in benzene
The mixt. of reagents in benzene was kept at 60°C for 3 d;; evapd., washed with benzene, pentane at -78°C;;
参考文献
Beachley, O. T.; Kopasz, John P.; Zhang, Hongming; Hunter, William E.; Atwood, Jerry L.
Journal of Organometallic Chemistry, 1987 , vol. 325, p. 69 - 82
NH3 in benzene
A glass bomb is charged with the organo Ta compd., evacuated, benzene introduced by distn.. NH3 is condensed into the vessel at -198°C. Mixture is stirred at 20° for 18 h, heated to 80°C for 11 h and cooled to 23°C; filtn. of solid, washing (hexane), elem. anal.;
参考文献
Holl, Mark M. Banaszak; Kersting, Meinolf; Pendley, Bradford D.; Wolczanski, Peter T.
Inorganic Chemistry, 1990 , vol. 29, p. 1518 - 1526
DePuy, Charles H.; Gronert, Scott; Barlow, Stephan E.; Bierbaum, Veronica M.; Damrauer, Robert
Journal of the American Chemical Society, 1989 , vol. 111, # 6 p. 1968 - 1973
