N-(11-溴十一基)氨基甲酸叔丁酯合成路线 （共 5 条）
反应条件
N-bromosuccinmide; triphenylphosphine in benzene
T=23°C; 12 h;
参考文献
Belser, Thomas; Stoehr, Meike; Pfaltz, Andreas
Journal of the American Chemical Society, 2005 , vol. 127, # 24 p. 8720 - 8731
反应条件
triethylamine in tetrahydrofuran; water
T=0 - 20°C; Inert atmosphere;
参考文献
Hofmann, Andreas; Graf, Christina; Kung, Shih-Hao; Kim, Myeongseob; Peng, Xiaogang; El-Aama, Randa; Ruehl, Eckart
Synthesis, 2010 , # 7 art. no. T15909SS, p. 1150 - 1158
反应条件
1: 53 percent / LiAlH4 / tetrahydrofuran / 6 h / 67 °C
2: 89 percent / Et3N / CH2Cl2 / 10 h / 0 - 23 °C
3: 74 percent / N-bromosuccinimide; Ph3P / benzene / 12 h / 23 °C
View Scheme
参考文献
Belser, Thomas; Stoehr, Meike; Pfaltz, Andreas
Journal of the American Chemical Society, 2005 , vol. 127, # 24 p. 8720 - 8731
反应条件
1: 89 percent / Et3N / CH2Cl2 / 10 h / 0 - 23 °C
2: 74 percent / N-bromosuccinimide; Ph3P / benzene / 12 h / 23 °C
View Scheme
参考文献
Belser, Thomas; Stoehr, Meike; Pfaltz, Andreas
Journal of the American Chemical Society, 2005 , vol. 127, # 24 p. 8720 - 8731
反应条件
sodium hydroxide; dihydrogen peroxide; triphenylphosphine in tetrahydrofuran; dichloromethane
参考文献
Bayer Aktiengesellschaft; UNIVERSITE LIBRE DE BRUXELLES; Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek; SIGMA COATINGS B.V.; Atofina
Patent: EP1245558 A1, 2002 ;
