反式-1,3-二苯基-2-丙烯-1-醇合成路线 （共 38 条）
反应条件
silica gel; sodium cyanoborohydride
0.0208333 h; Neat (no solvent)Microwave irradiation; regioselective reaction;
参考文献
Kouhkan, Mehri; Zeynizadeh, Behzad
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 10 p. 2961 - 2966
反应条件
hydrogen; palladium-copper; silica gel in ethanol
T=25°C; P=760.051 Torr;
参考文献
Spee; Boersma; Meijer; Slagt; Van Koten; Geus
Journal of Organic Chemistry, 2001 , vol. 66, # 5 p. 1647 - 1656
反应条件
hydrogen; palladium-copper; silica gel in ethanol
T=25°C; P=760 Torr; Kinetics;
参考文献
Spee; Boersma; Meijer; Slagt; Van Koten; Geus
Journal of Organic Chemistry, 2001 , vol. 66, # 5 p. 1647 - 1656
反应条件
Rh2(trifluoroacetate)4(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)2; potassium tert-butylate in methanol
T=65°C; 6 h; Inert atmosphere;
参考文献
Trindade, Alexandre F.; Andre, Vania; Duarte, M. Teresa; Veiros, Luis F.; Gois, Pedro M.P.; Afonso, Carlos A.M.
Tetrahedron, 2010 , vol. 66, # 44 p. 8494 - 8502
反应条件
(Ph)2SiH2; cesium fluoride
T=0°C; 1 h;
参考文献
Corriu, R. J. P.; Perz, R.; Reye, C.
Tetrahedron, 1983 , vol. 39, # 6 p. 999 - 1010
反应条件
1: With cerium(III) chloride in tetrahydrofuran
T=-78°C; 3 h;
2: With sodium tetrahydroborate; cerium(III) chloride in methanol
参考文献
Kojima, Satoshi; Hidaka, Tsugihiko; Yamakawa, Atsushi
Chemistry Letters, 2005 , vol. 34, # 4 p. 470 - 471
反应条件
hydrogen; platinum in ethyl acetate
P=1520.1 Torr;
参考文献
Gutierrez; Nazareno; Sosa; Lopez De Mishima; Mishima
Electrochimica Acta, 2010 , vol. 55, # 20 p. 5831 - 5839
反应条件
tBuOOLi in tetrahydrofuran
T=-78 - 20°C; 24 h;
参考文献
Evans, Paul; Taylor, Richard J. K.
Tetrahedron Letters, 1997 , vol. 38, # 17 p. 3055 - 3058
反应条件
1: in tetrahydrofuran
T=0°C; Inert atmosphere;
2: With water; ammonium chloride in tetrahydrofuran
Inert atmosphere;
参考文献
Bartoszewicz, Agnieszka; Martin-Matute, Belen
Organic Letters, 2009 , vol. 11, # 8 p. 1749 - 1752
反应条件
1.1: n-butyllithium / diethyl ether; hexane / -78 - 0 °C
1.2: 75 percent / diethyl ether; hexane / 2 h / 0 °C
2.1: 88 percent / hydrogen / PdCu/SiO2 / ethanol / 25 °C / 760.05 Torr
View Scheme
参考文献
Spee; Boersma; Meijer; Slagt; Van Koten; Geus
Journal of Organic Chemistry, 2001 , vol. 66, # 5 p. 1647 - 1656
