反应条件
1.1: LDA / tetrahydrofuran; hexane / 1 h / 0 °C 1.2: 80 percent / tetrahydrofuran; hexane / 1 h / 20 °C 2.1: 43 percent / p-toluenesulfonic acid monohydrate; triethyl orthoformate / CH2Cl2 / 19 h / 25 °C 3.1: 77 percent / potassium bis(trimethylsilyl)amide / diethyl ether; toluene / 2 h / 20 °C 4.1: 80 percent / aq. AcOH / 4 h / Heating 5.1: 97 percent / L-selectride / tetrahydrofuran / 17 h / 0 °C 6.1: diphenylphosphoryl azide; diethyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 17 h / 20 °C 7.1: LiAlH4 / ethanol; diethyl ether / 2 h / 20 °C 8.1: 528 mg / Et3N; DMAP / CH2Cl2 / 17 h / 20 °C 9.1: 83 percent / sodium hydroxide; tetrabutylammonium bromide / toluene; H2O / 0.67 h / 100 °C 10.1: 85 percent / O3; triphenylphosphine / CH2Cl2 / 9 h / -78 - 20 °C 11.1: 92 percent / potassium carbonate; tetrabutylammonium bromide / toluene / 2 h / Heating 12.1: 92 percent / sodium borohydride / ethanol / 1 h / 0 °C 13.1: 70 percent / boron tribromide / CH2Cl2 / 1 h / -40 °C 14.1: Red-Al / toluene / 0.5 h / Heating 15.1: 77 mg / Et3N / CH2Cl2 / 1 h / 25 °C 16.1: 75 percent / hydrogen peroxide / [(C8H17)3NCH3]+3[PO4[W(O)(O2)2]4]3- / 1,2-dichloro-ethane; H2O / 2 h / Heating 17.1: 75 percent / sodium borohydride / ethanol / 2 h / Heating 18.1: sodium periodate; aq. NaHCO3 / tetrahydrofuran / 0.5 h / 25 °C 19.1: 3.9 mg / aq. NaHCO3 / benzene / 0.75 h / Heating 20.1: MnO2 / CH2Cl2 / 0.25 h / 25 °C 20.2: 75 percent / LiAlH4 / tetrahydrofuran / 0.25 h / Heating View Scheme
参考文献
Taber, Douglass F.; Neubert, Timothy D.; Rheingold, Arnold L.
Journal of the American Chemical Society, 2002 , vol. 124, # 42 p. 12416 - 12417
