3,5,5-三甲基-3-环己烯-1-酮合成路线 （共 14 条）
反应条件
formic acid; dihydrogen peroxide
参考文献
Huels Aktiengesellschaft
Patent: US4898984 A1, 1990 ;
反应条件
oxygen; triethylamine; iron tetrasulfophthalocyanine-TiO2 in dimethyl sulfoxide T=60°C; P=1500.12 Torr; 24 h;
参考文献
New Journal of Chemistry, , vol. 29, # 10 p. 1245 - 1248
反应条件
dihydrogen peroxide; MgLa-3 in methanol T=19.85°C; 24 h; Product distribution; Further Variations:CatalystsTemperatures;
参考文献
Journal of Catalysis, , vol. 211, # 1 p. 150 - 156
反应条件
2,6-dimethyl-4-heptanone; oxygen; 1,4-diaza-bicyclo[2.2.2]octane T=40°C; 5 h;
参考文献
Daicel Chemical Industries, Ltd.
Patent: US6346651 B1, 2002 ;
Location in patent: Page column 15-17 ;
反应条件
oxygen; triethylamine; iron tetrasulfophthalocyanine-TiO2 in dimethyl sulfoxide T=60°C; P=1500.12 Torr; 24 h;
参考文献
New Journal of Chemistry, , vol. 29, # 10 p. 1245 - 1248
反应条件
tert.-butylhydroperoxide; silica gel; Titanium(IV) oxide in ethylbenzene T=79.85°C; Isomerization; oxidation; 0.208333 h; Product distribution; Further Variations:Catalyststime;
参考文献
Beck; Mallat; Baiker
Journal of Catalysis, 2000 , vol. 195, # 1 p. 79 - 87
反应条件
methylmagnesium bromide; acetic acid
Isomerization;
参考文献
Constantino, Mauricio Gomes; Donate, Paulo Marcos; Frederico, Daniel; Carvalho, Tecia Vieira; Cardoso, Luiz Eduardo; Zukerman-Schpector, Julio
Synthetic Communications, 2000 , vol. 30, # 18 p. 3327 - 3340
反应条件
tert.-butylhydroperoxide; titanium silicalite in ethylbenzene
T=60°C; Yield given. Title compound not separated from byproducts;
参考文献
Hutter, R.; Mallat, T.; Baiker, A.
Journal of the Chemical Society, Chemical Communications, 1995 , # 24 p. 2487 - 2488
反应条件
diethyl ether; iron(III) chloride
参考文献
Kharasch; Tawney
Journal of the American Chemical Society, 1941 , vol. 63, p. 2308,2313
Journal of the American Chemical Society, 1945 , vol. 67, p. 128,130
参考文献
Kharasch; Tawney
Journal of the American Chemical Society, 1941 , vol. 63, p. 2308,2313
Journal of the American Chemical Society, 1945 , vol. 67, p. 128,130
Full Text Show Details
Kharasch et al.
Journal of Organic Chemistry, 1956 , vol. 21, p. 322 Anm. 4
