2,6,6-三甲基-1-环己烯基乙醛合成路线 （共 26 条）
反应条件
perchloric acid in tetrahydrofuran 0.5 h; Ambient temperature;
参考文献
Lee, Eun; Shin, In-Jae; Kim, Tae-Seong
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 260 - 264
反应条件
1: s-BuLi / 1.) THF, hexane, from -70 deg C to -25 deg C, 2.) -25 deg C, 0.5 h 2: 75 percent / 90percent aq. formic acid / 0.17 h / Ambient temperature View Scheme
参考文献
Lee, Eun; Shin, In-Jae; Kim, Tae-Seong
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 260 - 264
反应条件
vanadium tri-n-propoxide; benzoic acid; hydroxytriphenylsilane in various solvent(s) T=140 - 150°C;
参考文献
Jalali-Naini, M.; Guillerm, D.; Lallemand, J-Y.
Tetrahedron, 1983 , vol. 39, # 5 p. 749 - 758
反应条件
titanium tetra-n-butoxide; 4-methyl-benzoic acid; copper(l) chloride in 1,2-dichloro-benzene T=130°C; 4 h; Title compound not separated from byproducts;
参考文献
Chabardes, Pierre
Tetrahedron Letters, 1988 , vol. 29, # 48 p. 6253 - 6256
反应条件
formic acid 0.166667 h; Ambient temperature;
参考文献
Jong, Johannes C. de; Wildeman, Jurjen; Leusen, Albert M. van; Feringa, Ben L.
Synthetic Communications, 1990 , vol. 20, # 4 p. 589 - 596
反应条件
1: 92 percent / NaOH, Br2 / H2O; dioxane / 4 h / Ambient temperature 2: 1.) Et3N, diphenyl phosphoryl azide, 2.) 0.5 N aq. HCl / 1) dioxan, RT, 1 h, 2.) reflux, 15 min View Scheme
参考文献
Jong, Johannes C. de; Wildeman, Jurjen; Leusen, Albert M. van; Feringa, Ben L.
Synthetic Communications, 1990 , vol. 20, # 4 p. 589 - 596
反应条件
quinoline; Petroleum ether bei partieller Hydrierung an bleihaltigem Palladium, anschl. mit wss. H2SO4;
参考文献
Isler et al.
Helvetica Chimica Acta, 1956 , vol. 39, p. 274,276
Justus Liebigs Annalen der Chemie, 1957 , vol. 603, p. 129,133
反应条件
hydrogenchloride; diphenyl phosphoryl azide; triethylamine 1) dioxan, RT, 1 h, 2.) reflux, 15 min; Yield given. Multistep reaction;
参考文献
Jong, Johannes C. de; Wildeman, Jurjen; Leusen, Albert M. van; Feringa, Ben L.
Synthetic Communications, 1990 , vol. 20, # 4 p. 589 - 596
反应条件
hydrogenchloride; water
参考文献
Landor; Landor
Journal of the Chemical Society, 1956 , p. 1015,1018
反应条件
1: zinc oxide; silicon oil / 200 °C / Erhitzen unter vermindertem Druck 2: HCl; water View Scheme
参考文献
Landor; Landor
Journal of the Chemical Society, 1956 , p. 1015,1018
