DL-2,3-二羟基丙酸合成路线 (共 157 条)
反应条件
sodium hydroxide; N-chloro-4-methylbenzenesulfonamide in water T=35°C; 24 h; Product distribution;
参考文献
Rangappa, Kanchugarakoppal S.; Manjunathaswamy, Huchappa; Raghavendra, Manikanahally P.; Gowda, D. Channe
Carbohydrate Research, 1998 , vol. 307, # 3-4 p. 253 - 262
反应条件
sodium hydroxide; air in water T=100°C; 2 h; other reagent: Ca(OH)2, air absence; Mechanism;
参考文献
Niemelae, Klaus
Carbohydrate Research, 1996 , vol. 285, p. 41 - 48
反应条件
tris(.mu.-oxo)di[(1,4,7-trimethyl-1,4,7-triazanonane)manganese(IV)] hexafluorophosphate; dihydrogen peroxide; oxalic acid in water; acetonitrile T=22°C; 0.5 h; Kinetics; ConcentrationReagent/catalystTime;
参考文献
Shul'Pin, Georgiy B.; Kozlov, Yuriy N.; Shul'Pina, Lidia S.; Strelkova, Tatyana V.; Mandelli, Dalmo
Catalysis Letters, 2010 , vol. 138, # 3-4 p. 193 - 204
反应条件
in water addn. of glycerol to CrO3 and H3PO4 soln. (molar ratio Cr/P=ca 1, glycerine/Cr>= 1), evapn., heating for 2 h at 800-950°C; detd. by thermal analysis, EPR spectroscopy and X-ray diffraction;
参考文献
Vykhodtseva; Tarasova; Yakovleva; Soderzhinova; Dulina
Inorganic Materials, 1998 , vol. 34, # 5 p. 491 - 495
反应条件
Fe2(S04)3 in sulfuric acid T=100°C; effect of the temp., the time and the concentration of the reactants; comparison with the oxidation with Ce(SO4)2*4H2O; Rate constantThermodynamic dataProduct distribution;
参考文献
Krupenskii, V. I.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 10 p. 2412 - 2415,2132 - 2135
反应条件
pyridine-2-carboxylic acid; sodium 4-picolinate T=39.85°C; Oxidation; pH=6.1; Activation energyKinetics; Further Variations:pH-valuesTemperatures;
参考文献
Gupta, Kalyan Kali Sen; Begum, Bilkis Ara
Carbohydrate Research, 1999 , vol. 315, # 1-2 p. 70 - 75
参考文献
Melikow
Chemische Berichte, 1880 , vol. 13, p. 273
参考文献
Gmelin Handbook: N: MVol.4, 7.7, page 1006 - 1013
反应条件
copper(II) sulfate T=100°C; study of the oxidation reaction of D-lyxose by cupric ion, kinetic mesurements, ΔS(excit.),; Product distributionRate constantThermodynamic data;
参考文献
Krupenskii, V. I.
J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 7 p. 1658 - 1660,1479 - 1481
参考文献
Klebs
Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1894 , vol. 19, p. 330