(3beta,5alpha,24R)-麦角甾烷-3-醇合成路线 （共 9 条）
反应条件
ammonium formate; palladium on activated charcoal in dichloromethane 5 h; Irradiation;
参考文献
Dayal; Ertel; Rapole; Asgaonkar; Salen
Steroids, 1997 , vol. 62, # 5 p. 451 - 454
反应条件
acetic acid; platinum T=20°C; Hydrogenation.Hydrolyse des erhaltenen O-Acetyl-Derivats;
参考文献
Fernholz; Ruigh
Journal of the American Chemical Society, 1941 , vol. 63, p. 1157
反应条件
acetic acid; platinum T=70°C; Hydrogenation.sowie bei 80grad; Hydrolyse des erhaltenen O-Acetyl-Derivats;
参考文献
Bergmann
Journal of Biological Chemistry, 1934 , vol. 104, p. 553,556
Full Text Show Details
Bergmann; Schedl; Low
Journal of Organic Chemistry, 1945 , vol. 10, p. 587,590
Full Text Show Details
Bergmann; Dusza
Justus Liebigs Annalen der Chemie, 1957 , vol. 603, p. 36,41
反应条件
1: 4 mg / pyridine / 24 h / 90 °C 2: pyridine / Ambient temperature 3: hydrogen / Pd-C / ethanol / Ambient temperature 4: 1.) TsX, 2.) lithium aluminium hydride View Scheme
参考文献
D'Auria, Maria V.; Finamore, Ester; Minale, Luigi; Pizza, Cosimo; Riccio, Raffaele; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2277 - 2282
反应条件
acetic acid; platinum T=20°C; Hydrogenation.Hydrolyse des erhaltenen O-Acetyl-Derivats;
参考文献
Bergmann et al.
Journal of Organic Chemistry, 1944 , vol. 9, p. 287
Journal of Organic Chemistry, 1945 , vol. 10, p. 575,578
反应条件
hydrogen; palladium on activated charcoal Ambient temperature;
参考文献
D'Auria, Maria V.; Finamore, Ester; Minale, Luigi; Pizza, Cosimo; Riccio, Raffaele; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2277 - 2282
反应条件
ethyl acetate; platinum Hydrogenation.Hydrolyse des erhaltenen O-Acetyl-Derivats;
参考文献
Bergmann; Gould; Low
Journal of Organic Chemistry, 1945 , vol. 10, p. 570,577
反应条件
2: platinum; glacial acetic acid / 70 °C / Hydrogenation.sowie bei 80grad; Hydrolyse des erhaltenen O-Acetyl-Derivats View Scheme
参考文献
Bergmann; Schedl; Low
Journal of Organic Chemistry, 1945 , vol. 10, p. 587,590
反应条件
1: HCl; chloroform / 0 °C 2: platinum; glacial acetic acid / 20 °C / Hydrogenation.Hydrolyse des erhaltenen O-Acetyl-Derivats View Scheme
参考文献
Bergmann et al.
Journal of Organic Chemistry, 1944 , vol. 9, p. 287
Journal of Organic Chemistry, 1945 , vol. 10, p. 575,578
