in toluene byproducts: SEt2; (N2); using Schlenk techniques; addn. of PdCl2(SEt2)2 (1 equiv.) to soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene; stirring for 30 minat room temp.; concn., addn. of Et2O, pptn., concn. of soln., addn. of pentane, pptn., elem. anal.;

in benzene byproducts: PPh3; (N2); using Schlenk techniques; addn. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) to soln. of NiCl2(PPh3)2 (1 equiv.) in benzene; stirring for 30 minat room temp.; concn., extn. with Et2O, pptn., concn. of soln., elem. anal.;

in toluene byproducts: tht; (N2); using Schlenk techniques; addn. of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene to soln. of AuCl3(tht) (1 equiv.) in toluene atroom temp.; pptn., sepn., washing with Et2O, drying in vac., evapn. of mother liquorto dryness, pptn., elem. anal.;

in toluene (N2); using Schlenk techniques; addn. of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene to soln. of anhyd. FeCl3 (1 equiv.) in degassed, dry toluene; stirring for 5 h at room temp.; removal of solvent in vac., extn. with degassed, dry Et2O, pptn., transferring of soln. to another flask by cannula, concn., cooling at -20°C, crystn.;

in tetrahydrofuran (N2); using Schlenk techniques; treatment of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in THF with soln. of TiCl3(OCHMe2) (1 equiv.) in THF at -78°C;

in benzene-d6 byproducts: SEt2; (N2); using Schlenk techniques; mixing of PtCl2(SEt2)2 and Au(C6H3(CH2NMe2)2)(PPh3) in 1:1 molar ratio in C6D6; reflux for 2 h; detected by NMR;

in toluene

in benzene-d6 byproducts: SEt2; (N2); using Schlenk techniques; mixing of PtCl2(SEt2)2 and Au(C6H3(CH2NMe2)2)(PPh3) in 1:1 molar ratio in C6D6; reflux for 2 h; detected by NMR;

in toluene byproducts: SEt2; (N2); using Schlenk techniques; addn. of PdCl2(SEt2)2 (1 equiv.) to soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene; stirring for 30 minat room temp.; concn., addn. of Et2O, pptn., concn. of soln., addn. of pentane, pptn., elem. anal.;