5-溴-3'-癸基-2,2':5',2''-三联噻吩合成路线 （共 4 条）
反应条件
bis(trimethylsilyl)-sulfide; boron trichloride in hexane; toluene T=20°C; 1 h;
参考文献
Von Kieseritzky, Fredrik; Hellberg, Jonas; Wang, Xiangjun; Inganaes, Olle
Synthesis, 2002 , # 9 p. 1195 - 1200
反应条件
1.1: 100 percent / AlCl3 / benzene / 0.5 h / Heating 2.1: 100 percent / Br2 / CH2Cl2 / 0.75 h / Heating 3.1: MeMgBr; Et2NH / toluene / 3 h / 0 °C 3.2: 63 percent / Et3N / toluene / 20 °C 4.1: 51 percent / hexamethyldisilathiane; BCl3 / toluene; hexane / 1 h / 20 °C View Scheme
参考文献
Von Kieseritzky, Fredrik; Hellberg, Jonas; Wang, Xiangjun; Inganaes, Olle
Synthesis, 2002 , # 9 p. 1195 - 1200
反应条件
1.1: 100 percent / Br2 / CH2Cl2 / 0.75 h / Heating 2.1: MeMgBr; Et2NH / toluene / 3 h / 0 °C 2.2: 63 percent / Et3N / toluene / 20 °C 3.1: 51 percent / hexamethyldisilathiane; BCl3 / toluene; hexane / 1 h / 20 °C View Scheme
参考文献
Von Kieseritzky, Fredrik; Hellberg, Jonas; Wang, Xiangjun; Inganaes, Olle
Synthesis, 2002 , # 9 p. 1195 - 1200
反应条件
1.1: MeMgBr; Et2NH / toluene / 3 h / 0 °C 1.2: 63 percent / Et3N / toluene / 20 °C 2.1: 51 percent / hexamethyldisilathiane; BCl3 / toluene; hexane / 1 h / 20 °C View Scheme
参考文献
Von Kieseritzky, Fredrik; Hellberg, Jonas; Wang, Xiangjun; Inganaes, Olle
Synthesis, 2002 , # 9 p. 1195 - 1200
