3-苄氧基-1,2-丙二醇合成路线 （共 49 条）
反应条件
1: With p-nitrosobenzene; DL-proline in acetonitrile T=-20°C; 24 h; 2: With sodium tetrahydroborate in methanol; acetonitrile 0.5 h; 3: With CuSO4‵5H2O in methanol T=0°C; 10 h;
参考文献
Sawant, Rajiv T.; Waghmode, Suresh B.
Tetrahedron, 2010 , vol. 66, # 11 p. 2010 - 2014
反应条件
1: 77 percent / t-BuOK / dimethylformamide / 1.5 h / -5 - 0 °C 2: 44 percent / DIBAL / diethyl ether; toluene / 4 h / 20 °C View Scheme
参考文献
Takano, Seiichi; Akiyama, Masashi; Sato, Seiji; Ogasawara, Kunio
Chemistry Letters, 1983 , p. 1593 - 1596
反应条件
iso-propylmagnesium bromide in various solvent(s) 2 h; -15 deg C - room temperature;
参考文献
Poppe; Recseg; Novak
Synthetic Communications, 1995 , vol. 25, # 24 p. 3993 - 4000
反应条件
copper acetylacetonate 4 h; Heating;
参考文献
Sirkecioglu, Okan; Karliga, Bekir; Talinli, Naciye
Tetrahedron Letters, 2003 , vol. 44, # 46 p. 8483 - 8485
反应条件
in benzyl alcohol 0.5 h; Heating;
参考文献
Birkofer, Leonhard; Stuhl, Oskar
Journal of Organometallic Chemistry, 1980 , vol. 187, # 1 p. 21 - 29
反应条件
1: O3; Me2S / CH2Cl2 / 1.25 h / -78 °C 2: NaBH4 / CH2Cl2; ethanol / 0.33 h / 0 °C 3: 80 percent / DIBALH / CH2Cl2; diethyl ether / 4 h / 20 °C View Scheme
参考文献
Marguet, Frank; Cavalier, Jean-Francois; Verger, Robert; Buono, Gerard
European Journal of Organic Chemistry, 1999 , # 7 p. 1671 - 1678
反应条件
1: O3; Me2S / CH2Cl2 / 1.25 h / -78 °C 2: NaBH4 / CH2Cl2; ethanol / 0.33 h / 0 °C View Scheme
参考文献
Marguet, Frank; Cavalier, Jean-Francois; Verger, Robert; Buono, Gerard
European Journal of Organic Chemistry, 1999 , # 7 p. 1671 - 1678
反应条件
1: NaBH4 / CH2Cl2; ethanol / 0.33 h / 0 °C 2: 80 percent / DIBALH / CH2Cl2; diethyl ether / 4 h / 20 °C View Scheme
参考文献
Marguet, Frank; Cavalier, Jean-Francois; Verger, Robert; Buono, Gerard
European Journal of Organic Chemistry, 1999 , # 7 p. 1671 - 1678
反应条件
Bacillus megaterium ECU1001 epoxide hydrolase in potassium phosphate buffer; dimethyl sulfoxide T=30°C; pH=7; 2 h; Resolution of racemateEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Zhao, Jing; Chu, Yan-Yan; Li, Ai-Tao; Ju, Xin; Kong, Xu-Dong; Pan, Jiang; Tang, Yun; Xu, Jian-He
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1510 - 1518
反应条件
in N,N-dimethyl-formamide Ambient temperature; Yields of byproduct given;
参考文献
Carlsen, Per H.; Aase, Kristin J.
Acta Chemica Scandinavica, 1993 , vol. 47, # 6 p. 617 - 619
