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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
表睾酮
合成路线
(共 22 条)
36025-82-8
→
反应条件
481-30-1
表睾酮
反应条件
potassium hydroxide in methanol T=65°C; 4 h;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 58, # 3 p. 600 - 611
958883-18-6
→
反应条件
107-86-8
3-甲基-2-丁烯醛
+
481-30-1
表睾酮
+
38978-06-2
反应条件
1: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane; water T=20°C; 6 h; 2: in dichloromethane T=20°C; 24 h; Further stages.;
参考文献
Tetrahedron, , vol. 63, # 45 p. 10921 - 10929
58-22-0
睾酮
→
反应条件
63-05-8
雄烯二酮
+
481-30-1
表睾酮
反应条件
unidentified fungal species isolated from grinded corn in water T=37°C; pH=7; 1 h; aq. phosphate bufferMicrobiological reactionEnzymatic reaction;
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
51067-43-7
16,17-环氧-4-雄甾烯-3-酮
→
反应条件
481-30-1
表睾酮
反应条件
manganese(IV) oxide; lithium aluminium tetrahydride
参考文献
Journal of the American Chemical Society, , vol. 77, p. 4145,4148
83-46-5
植物甾醇
→
反应条件
481-30-1
表睾酮
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 3: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
63-05-8
雄烯二酮
→
反应条件
481-30-1
表睾酮
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
58-22-0
睾酮
→
反应条件
481-30-1
表睾酮
反应条件
1: 100 percent / pyridine / 0.25 h / 0 - 20 °C 2: 76 percent / 18-crown-6 / benzene / 72 h / Heating 3: 5percent KOH / methanol / Heating View Scheme
参考文献
Tetrahedron Letters, , vol. 37, # 34 p. 6145 - 6148
182243-71-6
→
反应条件
481-30-1
表睾酮
反应条件
1: 76 percent / 18-crown-6 / benzene / 72 h / Heating 2: 5percent KOH / methanol / Heating View Scheme
参考文献
Tetrahedron Letters, , vol. 37, # 34 p. 6145 - 6148
897-06-3
雄甾-1,4-二烯-3,17-二酮
→
反应条件
481-30-1
表睾酮
反应条件
1: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 2: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction 3: unidentified fungal species isolated from grinded corn / water / 1 h / 37 °C / pH 7 / aq. phosphate buffer; Microbiological reaction; Enzymatic reaction View Scheme
参考文献
Journal of Steroid Biochemistry and Molecular Biology, , vol. 119, # 3-5 p. 161 - 170
1425-09-8
→
反应条件
481-30-1
表睾酮
反应条件
potassium hydroxide in methanol Heating; Yield given;
参考文献
Tetrahedron Letters, , vol. 37, # 34 p. 6145 - 6148
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