三甲基((4-((4-((4-(苯基乙炔)苯基)乙炔)苯基)乙炔)苯基)乙炔)硅烷合成路线 （共 3 条）
反应条件
1: trimethyl[4-(4-(phenylethynyl)phenylethynyl)phenylethynyl]silane With potassium hydroxide in tetrahydrofuran; methanol
T=25°C;
2: 4-(TMS-ethynyl)iodobenzene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine in tetrahydrofuran
T=25°C; Sonogashira coupling reaction;
参考文献
Zhi, Yong-Gang; Lai, Siu-Wai; Chan, Queenie K.-W.; Law, Yuen-Chi; Tong, Glenna S.-M.; Che, Chi-Ming
European Journal of Organic Chemistry, 2006 , # 14 p. 3125 - 3139
反应条件
1.1: KOH / methanol; tetrahydrofuran / 25 °C
1.2: Pd(PPh3)2Cl2; CuI; NHEt2 / tetrahydrofuran / 25 °C
2.1: KOH / methanol; tetrahydrofuran / 25 °C
2.2: Pd(PPh3)2Cl2; CuI; NHEt2 / tetrahydrofuran / 25 °C
View Scheme
参考文献
Zhi, Yong-Gang; Lai, Siu-Wai; Chan, Queenie K.-W.; Law, Yuen-Chi; Tong, Glenna S.-M.; Che, Chi-Ming
European Journal of Organic Chemistry, 2006 , # 14 p. 3125 - 3139
反应条件
1.1: KOH / methanol; tetrahydrofuran / 25 °C
1.2: Pd(PPh3)2Cl2; CuI; NHEt2 / tetrahydrofuran / 25 °C
2.1: KOH / methanol; tetrahydrofuran / 25 °C
2.2: Pd(PPh3)2Cl2; CuI; NHEt2 / tetrahydrofuran / 25 °C
3.1: KOH / methanol; tetrahydrofuran / 25 °C
3.2: Pd(PPh3)2Cl2; CuI; NHEt2 / tetrahydrofuran / 25 °C
View Scheme
参考文献
Zhi, Yong-Gang; Lai, Siu-Wai; Chan, Queenie K.-W.; Law, Yuen-Chi; Tong, Glenna S.-M.; Che, Chi-Ming
European Journal of Organic Chemistry, 2006 , # 14 p. 3125 - 3139
