1: 85 percent / Oxone(R) / acetone; H2O / 0 - 25 °C 2: 74 percent / cesium fluoride; BnEt3NCl / PdCl2(PPh3)2 / toluene; H2O / 7 h / Heating View Scheme

chloro{bis(2-norbornyl)phosphanyl}(2'-dimethylamino-1,1'-bip; henyl-2-yl)palladium(II)G (1 mol percent) in toluene T=95°C; 23 h;

potassium fluoride; tri-cyclo-hexyl-phosphine; palladium diacetate in toluene T=95°C; 55 h; under argon;