1: NH4Cl / Ambient temperature 2: <Pt<<(CH2=CH)Me2Si>2O>2> / toluene / 0.5 h / Ambient temperature 3: 30percent H2O2 / methanol; tetrahydrofuran; aq. KOH / 2.5 h / Ambient temperature 4: CSA / 4 h / Ambient temperature 5: cc HCl / diethyl ether / 5 h / Ambient temperature View Scheme
参考文献
Tamao, Kohei; Nakagawa, Yoshiki; Arai, Hitoshi; Higuchi, Noriko; Ito, Yoshihiko
Journal of the American Chemical Society, 1988 , vol. 110, p. 3712 - 3714
1: <Pt<<(CH2=CH)Me2Si>2O>2> / toluene / 0.5 h / Ambient temperature 2: 30percent H2O2 / methanol; tetrahydrofuran; aq. KOH / 2.5 h / Ambient temperature 3: CSA / 4 h / Ambient temperature 4: cc HCl / diethyl ether / 5 h / Ambient temperature View Scheme
参考文献
Tamao, Kohei; Nakagawa, Yoshiki; Arai, Hitoshi; Higuchi, Noriko; Ito, Yoshihiko
Journal of the American Chemical Society, 1988 , vol. 110, p. 3712 - 3714
hydrogen; ruthenium chloride supported on zirconia (3 wtpercent of ruthenium) and calcined at 500 C (ruthenium dispersion 40percent; chlorine content 50 ppm) in water T=60°C; P=36778.6 Torr; 100 h; Product distribution / selectivity;
参考文献
SK CORPORATION
Patent: WO2005/21475 A1, 2005 ;
Location in patent: Page/Page column 13-14 ;
hydrogenchloride in diethyl ether 5 h; Ambient temperature;
参考文献
Tamao, Kohei; Nakagawa, Yoshiki; Arai, Hitoshi; Higuchi, Noriko; Ito, Yoshihiko
Journal of the American Chemical Society, 1988 , vol. 110, p. 3712 - 3714