3-异丙基-6-甲基邻苯二酚合成路线 （共 20 条）
反应条件
1: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in tetrahydrofuran
T=20°C; Diels-Alder reaction; 24 h;
2: With trifluoroacetic acid
12 h; Further stages.;
参考文献
Gagnepain, Julien; Castet, Frederic; Quideau, Stephane
Angewandte Chemie - International Edition, 2007 , vol. 46, # 9 p. 1533 - 1535
反应条件
1: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in tetrahydrofuran
T=20°C; Diels-Alder reaction; 24 h;
2: With trifluoroacetic acid
12 h; Further stages.;
参考文献
Gagnepain, Julien; Castet, Frederic; Quideau, Stephane
Angewandte Chemie - International Edition, 2007 , vol. 46, # 9 p. 1533 - 1535
反应条件
1: With 2-iodoxybenzoic acid in tetrahydrofuran
T=20°C; 24 h;
2: With trifluoroacetic acid in tetrahydrofuran
12 h; Further stages.;
参考文献
Lebrasseur, Nathalie; Gagnepain, Julien; Ozanne-Beaudenon, Aurelie; Leger, Jean-Michel; Quideau, Stephane
Journal of Organic Chemistry, 2007 , vol. 72, # 16 p. 6280 - 6283
反应条件
1: With 2-iodoxybenzoic acid in tetrahydrofuran
T=20°C; 24 h;
2: With trifluoroacetic acid in tetrahydrofuran
12 h; Further stages.;
参考文献
Lebrasseur, Nathalie; Gagnepain, Julien; Ozanne-Beaudenon, Aurelie; Leger, Jean-Michel; Quideau, Stephane
Journal of Organic Chemistry, 2007 , vol. 72, # 16 p. 6280 - 6283
反应条件
air in isopropyl alcohol
T=20°C; 2 h; Irradiation;
参考文献
Chai, Wen; Takeda, Akihiro; Hara, Makoto; Ji, Shun-Jun; Horiuchi, C. Akira
Tetrahedron, 2005 , vol. 61, # 9 p. 2453 - 2463
反应条件
1: With 2-iodoxybenzoic acid in tetrahydrofuran
T=20°C; 24 h;
2: With trifluoroacetic acid in tetrahydrofuran
12 h; Further stages.;
参考文献
Gagnepain, Julien; Mereau, Raphael; Dejugnac, Delphine; Leger, Jean-Michel; Castet, Frederic; Deffieux, Denis; Pouysegu, Laurent; Quideau, Stephane
Tetrahedron, 2007 , vol. 63, # 28 p. 6493 - 6505
反应条件
D-glucose in aq. phosphate buffer
pH=7; Enzymatic reaction;
参考文献
Endoma, Mary Ann; Bui, Vu P.; Hansen, Jeff; Hudlicky, Tomas
Organic Process Research and Development, 2002 , vol. 6, # 4 p. 525 - 532
反应条件
3,3-dimethyldioxirane in acetone
参考文献
Crandall, Jack K.; Zucco, Martine; Scott Kirsch; Coppert, David M.
Tetrahedron Letters, 1991 , vol. 32, # 40 p. 5441 - 5444
反应条件
palladium on activated charcoal
T=230°C;
参考文献
Treibs; Albrecht
Journal fuer Praktische Chemie (Leipzig), 1959 , vol. <4> 8, p. 123,129
反应条件
1: 235 g / K2CO3 / acetone / 20 h / Heating
2: 82 g / polyphosphoric acid (84percent P4O10) / 16 h / 130 °C
3: O3 / acetic acid; H2O / 16 h / 15 °C
4: 61 percent / acetic acid; H2O / 60 h / 95 °C
5: 78 percent / NaOH, 30percent H2O2 / H2O / 2 h / 25 - 40 °C
View Scheme
参考文献
Dallacker; Coerver
1983 , vol. 38, # 10 p. 1243 - 1248
