3-甲基-6-(1-甲基乙亚基)环己-2-烯-1-酮合成路线 （共 58 条）
反应条件
formic acid in pentane
参考文献
BASF Aktiengesellschaft
Patent: US3962341 A1, 1976 ;
反应条件
N-benzyl-trimethylammonium hydroxide in tetrahydrofuran; methanol 1.33333 h; Heating;
参考文献
Nakanishi, Osamu; Fujitani, Mitsuji; Ichimoto, Itsuo; Ueda, Hiroo
Agricultural and Biological Chemistry, 1980 , vol. 44, # 7 p. 1667 - 1668
反应条件
oxalyl dichloride; dimethyl sulfoxide; triethylamine in dichloromethane T=-60 - 20°C; Swern oxidation;
参考文献
Baptistella, Lucia H. B.; Aleixo, Adriana M.
Synthetic Communications, 2002 , vol. 32, # 19 p. 2937 - 2950
反应条件
tert.-butylhydroperoxide; dipyridinium dichromate in benzene T=25°C; 9 h;
参考文献
Chidambaram, Nallaperumal; Chandrasekaran, Srinivasan
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 5048 - 5051
反应条件
barium dihydroxide; N-benzyl-N,N,N-triethylammonium chloride T=80°C; 1.5 h;
参考文献
Takasago International Corporation
Patent: US6342644 B1, 2002 ;
Location in patent: Example 2 ;
反应条件
sodium methylate in methanol 3 h; Ambient temperature;
参考文献
Mandai, Tadakatsu; Osaka, Kazuhito; Kawagishi, Makoto; Kawada, Mikio; Otera, Junzo
Synthetic Communications, 1984 , vol. 14, # 9 p. 797 - 804
反应条件
1: oxalyl chloride / benzene / a) 25 deg C, 2 h, b) 45 deg C, 30 min 2: 43 percent / Et3N / toluene / 3 h / Heating 3: 22 percent / NaOAc, Ac2O, AcOH / 12 h / Heating View Scheme
参考文献
Kulkarni, Yashwant S.; Niwa, Maho; Ron, Eyal; Snider, Barry B.
Journal of Organic Chemistry, 1987 , vol. 52, # 8 p. 1568 - 1576
反应条件
1: 43 percent / Et3N / toluene / 3 h / Heating 2: 22 percent / NaOAc, Ac2O, AcOH / 12 h / Heating View Scheme
参考文献
Kulkarni, Yashwant S.; Niwa, Maho; Ron, Eyal; Snider, Barry B.
Journal of Organic Chemistry, 1987 , vol. 52, # 8 p. 1568 - 1576
反应条件
1: chromyl acetate / acetic acid / a) 10 deg C, 10 h, b) RT, overnight 2: 61.2 percent Chromat. / phthalic acid / H2O View Scheme
参考文献
Boggiatto, Margarita V. de; Heluani, Carola S. de; Fenik, Ines J. S.; Catalan, Cesar A. N.
Journal of Organic Chemistry, 1987 , vol. 52, # 8 p. 1505 - 1511
反应条件
sodium acetate in acetic anhydride Heating;
参考文献
Beereboom,J.J.
Journal of Organic Chemistry, 1965 , vol. 30, p. 4230 - 4234
