2,4,6-三苯基三嗪合成路线 （共 216 条）
反应条件
in benzonitrile byproducts: 2,4,5-triphenylimidazole; conventional Schlenk technique; PhCN added with stirring to DyI2; 5 min;concd.; crystd. for 24 h; THF added to mother liquor; 1 h; decanted; so lvent removed from soln.; MeOH added; pptd. (20°C, 24 h); MeOH removed from soln.; pptd. by H2O; crystals after crystn. sepd. by decantation, washed with PhCN, dried (DyI3(PhCN)4); ppt. of Dy-THF complex washed with cold THF, dried in vac.; ppt. after H2O addition sepd. by centrifuging, washed with ether, dried (DyI(OH)2(H2O)11); elem. anal.;
参考文献
Balashova; Khoroshenkov; Kusyaev; Eremenko; Aleksandrov; Fukin; Bochkarev
Russian Chemical Bulletin, 2004 , vol. 53, # 4 p. 825 - 829
参考文献
Zhao, Fei; Zhan, Ming; Zhang, Wen-Xiong; Xi, Zhenfeng
Organometallics, 2013 , vol. 32, # 7 p. 2059 - 2068
参考文献
Zhao, Fei; Zhan, Ming; Zhang, Wen-Xiong; Xi, Zhenfeng
Organometallics, 2013 , vol. 32, # 7 p. 2059 - 2068
参考文献
Zhao, Fei; Zhan, Ming; Zhang, Wen-Xiong; Xi, Zhenfeng
Organometallics, 2013 , vol. 32, # 7 p. 2059 - 2068
参考文献
Johnson; Bass
Journal of the American Chemical Society, 1922 , vol. 44, p. 1343
反应条件
0.25 h; oil bath at 190 - 200 deg C; Further byproducts given;
参考文献
Hunter, Daniel; Neilson, Douglas G.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 2779 - 2783
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Abraham, Tonson
Monatshefte fuer Chemie, 1982 , vol. 113, p. 371 - 374
反应条件
in diethyl ether reagents ratio, time; Product distribution;
参考文献
Cook, Lawrence S.; Wakefield, Basil J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 2392 - 2397
参考文献
Cook, Lawrence S.; Prudhoe, Gordon; Venayak, Narinder D.; Wakefield, Basil J.
Journal of Chemical Research, Miniprint, 1982 , # 5 p. 1357 - 1367
反应条件
in benzonitrile byproducts: 2,3,5,6-tetraphenylpyrazine; conventional Schlenk technique; PhCN added with stirring to Tm compd.; 5min; concd.; crystd. for 24 h; THF added to mother liquor; 1 h; decante d; solvent removed from soln.; MeOH added; pptd. (20°C, 24 h); MeOH removed from soln.; pptd. by H2O; crystals after crystn. sepd. by decantation, washed with PhCN, dried (TmI3(PhCN)4); ppt. of Tm-THF complex washed with cold THF, dried in vac.; ppt. after H2O addition sepd. by centrifuging, washed with ether, dried (TmI(OH)2(H2O)5); elem. anal.;
参考文献
Balashova; Khoroshenkov; Kusyaev; Eremenko; Aleksandrov; Fukin; Bochkarev
Russian Chemical Bulletin, 2004 , vol. 53, # 4 p. 825 - 829
