1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 48 h / 85 °C / |Inert atmosphere 2: N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile / acetonitrile / 2 h / 90 °C / |Inert atmosphere 3: dihydrogen peroxide / dimethyl sulfoxide / 336 h / 20 °C 4: hydrogen bromide / dimethyl sulfoxide / 20 °C View Scheme

palladium on activated charcoal; ethanol Hydrogenation;

in water pH=6.96; Photolysisaq. phosphate buffer;

water; sodium hydroxide T=25°C; Kinetics; Concentration;

in water pH=6.96; Photolysisaq. phosphate buffer; Quantum yield;

toluene-4-sulfonic acid in N,N-dimethyl-formamide Ambient temperatureovernight;

iron potassium sulfate; water