3-甲基-1-(2,4,6-三羟基-3-甲基苯基)-1-丁酮合成路线 （共 3 条）
→
130288-57-2(2alpha,4alpha,4abeta,9abeta)-(+)-2,3,4,4a,9,9a-六氢-6,8-二羟基-3,3,4a-三甲基-7-(3-甲基-1-氧代丁基)-2,4-甲桥-1H-氧杂蒽-5-甲醛
反应条件
1: 41.6 percent / TiCl4 / CH2Cl2 / 2 h / -20 °C 2: Et4NOTs, DDQ / nitromethane / Ambient temperature; electrolysis: <poly(tetrafluoroethylene)>fibre coated glassy carbon anode, Pt cathode, 2.2 F View Scheme
参考文献
Chiba, Kazuhiro; Arakawa, Takaaki; Tada, Masahiro
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2939 - 2942
反应条件
titanium tetrachloride in dichloromethane
参考文献
Chiba, Kazuhiro; Arakawa, Takaaki; Tada, Masahiro
Chemical Communications, 1996 , # 15 p. 1763 - 1764
反应条件
aluminium trichloride
参考文献
Umehara, Kazuhiro; Singh, Inder Pal; Etoh, Hideo; Takasaki, Midori; Konoshima, Takao
Phytochemistry, 1998 , vol. 49, # 6 p. 1699 - 1704
