反应条件
sodium hydroxide; dihydrogen peroxide; dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) in tetrahydrofuran To a soln. of haloalkene is added 9-BBN at 0°C, mixt. is stirred for 5 h at room temp., catalyst and aq. NaOH are added, after refluxing for 14 h, the unreacted borane is oxidized with H2O2 for 1h.; Isolated by chromy. over silica gel with hexane-ether, identified by IR,(1)H NMR, mass spectrometry, elem. anal.;
参考文献
Miyaura, Norio; Ishiyama, Tatsuo; Sasaki, Hirotomo; Ishikawa, Masako; Satoh, Makoto; Suzuki, Akira
Journal of the American Chemical Society, 1989 , vol. 111, # 1 p. 314 - 321
