6,6'-二溴-2,2'-联吡啶合成路线 （共 29 条）
参考文献
Burstall
Journal of the Chemical Society, 1938 , p. 1662,1669
反应条件
n-butyllithium (n-hexane); phosphorus trichoride 1.) diethyl ether, -60 deg C, 2 h, 2.) diethyl ether, -40 deg C, 22 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Uchida; Okabe; Kobayashi; Oae
Synthesis, 1995 , # 8 p. 939 - 940
反应条件
n-butyllithium (n-hexane); phosphorus trichoride 1.) diethyl ether, -60 deg C, 2 h, 2.) diethyl ether, -40 deg C, 22 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Uchida; Okabe; Kobayashi; Oae
Synthesis, 1995 , # 8 p. 939 - 940
反应条件
1: 96 percent / hydrazine hydrate / 6 h / Heating 2: 90 percent / NaNO2; conc. HCl / H2O / 6 h / 0 - 20 °C View Scheme
参考文献
Shimada, Hiroshi; Sakurai, Toshihiko; Kitamura, Yusuke; Matsuura, Hirotaka; Ihara, Toshihiro
Dalton Transactions, 2013 , vol. 42, # 45 p. 16006 - 16013
反应条件
ammonia; KNH2; iron nitrate (III) in toluene T=-33°C; 4 h;
参考文献
Thibault, Michelle E.; Luska, Kylie L.; Schlaf, Marcel
Synthesis, 2007 , # 5 p. 791 - 793
反应条件
copper(l) iodide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran 10 h; Ambient temperature;
参考文献
Ziessel, Raymond; Suffert, Jean; Youinou, Marie-Therese
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6535 - 6546
反应条件
tetrakis(triphenylphosphine) palladium(0) in toluene T=122°C; 36 h;
参考文献
Baxter, Paul N. W.
Chemistry - A European Journal, 2002 , vol. 8, # 22 p. 5250 - 5264
反应条件
phenyllithium in tetrahydrofuran; diethyl ether; cyclohexane T=-85 - -80°C; 1 h;
参考文献
Garber, Ty; Rillema, D. Paul
Synthetic Communications, 1990 , vol. 20, # 8 p. 1233 - 1239
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=10 - 20°C;
参考文献
Ichikawa, Musubu; Wakabayashi, Kenta; Hayashi, Shuichi; Yokoyama, Norimasa; Koyama, Toshiki; Taniguchi, Yoshio
Organic Electronics: physics, materials, applications, 2010 , vol. 11, # 12 p. 1966 - 1973
反应条件
1: 92 percent / 5 h / 0 °C
2: H2O2
View Scheme
参考文献
Ziessel, Raymond
Tetrahedron Letters, 1989 , vol. 30, # 4 p. 463 - 466
