反式-2-甲基-2-丁烯醛合成路线 （共 86 条）
反应条件
2: MnO2 / pentane 3: HCO2H, H3PO4 4: (i), (ii) I2 View Scheme
参考文献
deVries,L.
Journal of Organic Chemistry, 1960 , vol. 25, p. 1838
反应条件
1: 54 percent / LiAlH4 / diethyl ether / 1.5 h / Ambient temperature 2: 87 percent / pyridine, p-(dimethylamino)pyridine / Ambient temperature View Scheme
参考文献
Rowan, Daryl D.; Lane, Heather P.; Allen, John M.; Fielder, Simon; Hunt, Martin B.
Journal of Agricultural and Food Chemistry, 1996 , vol. 44, # 10 p. 3276 - 3285
反应条件
potassium tert-butylate 1) THF, -78 deg C 2) THF, -78 deg C -> room temperature; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 31, # 10 p. 1405 - 1408
反应条件
hydrogenchloride in water; toluene T=150°C; Diels-Alder reaction;
参考文献
Buchanan, Grant S.; Cole, Kevin P.; Li, Gang; Tang, Yu; You, Ling-Feng; Hsung, Richard P.
Tetrahedron, 2011 , vol. 67, # 52 p. 10105 - 10118
反应条件
ammonium acetate in formamide T=80°C; 6 h;
参考文献
Sasaki, Isabelle; Vendier, Laure; Sournia-Saquet, Alix; Lacroix, Pascal G.
European Journal of Inorganic Chemistry, 2006 , # 16 p. 3294 - 3302
反应条件
1: tBuOLi / hexane / 20 °C 2: aq. NaOH / ethanol / 50 °C View Scheme
参考文献
Ohata, Kohei; Terashima, Shiro
Tetrahedron Letters, 2006 , vol. 47, # 16 p. 2787 - 2791
反应条件
in tetrahydrofuran T=-78°C; 1 h;
参考文献
Fleming, Fraser F.; Liu, Wang; Ghosh, Somraj; Steward, Omar W.
Journal of Organic Chemistry, 2008 , vol. 73, # 7 p. 2803 - 2810
反应条件
in diethyl ether T=-5 - 0°C; Inert atmosphere;
参考文献
Pulis, Alexander P.; Aggarwal, Varinder K.
Journal of the American Chemical Society, 2012 , vol. 134, # 27 p. 11298 - 11298
参考文献
Hull, Caroline; Mortlock, Simon V.; Thomas, Eric J.
Tetrahedron, 1989 , vol. 45, # 4 p. 1007 - 1016
参考文献
v. Miller
Chemische Berichte, 1890 , vol. 23, p. 2272
