反式-2-甲基-2-丁烯醛合成路线 （共 86 条）
反应条件
Saccharomyces cerevisiae; [14C]-Sucrose in water T=30°C; 18 h;
参考文献
Ferraboschi, Patrizia; Grisenti, Paride; Casati, Rosangela; Fiecchi, Alberto; Santaniello, Enzo
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 1743 - 1748
反应条件
sulfuric acid T=50°C; P=51754.1 Torr;
参考文献
Woo, Edmund P.; Cheng, Frank C.W.
Journal of Organic Chemistry, 1986 , vol. 51, # 19 p. 3706 - 3707
反应条件
1: benzene / 6 h / Heating 2: 1.) LDA, 3.) oxalic acid 3: 1.) n-BuLi / 1.) Et2O, hexane, RT, 10 min, 2.) Et2O, hexane, reflux, 12 h View Scheme
参考文献
Peterson, Thomson H.; Carpenter, Barry K.
Journal of the American Chemical Society, 1993 , vol. 115, # 13 p. 5466 - 5478
反应条件
in tetrahydrofuran T=0°C; 4 h;
参考文献
Gau, Ay-Hua; Lin, Guey-Liang; Uang, Biing-Jiun; Liao, Fen-Ling; Wang, Sue-Lein
Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2194 - 2201
反应条件
1: aqueous hydrochloric acid
2: CrO3; aqueous H2SO4
3: soda lime
View Scheme
参考文献
Poth et al.
Journal of the American Chemical Society, 1930 , vol. 52, p. 1239,1249
反应条件
sulfuric acid; iron(III) chloride; acetic acid
und Zinkchlorid;
参考文献
Tamura; Yamasaki
Yakugaku Zasshi, 1956 , vol. 76, p. 915
Chem.Abstr., 1957 , p. 2782
反应条件
1: 88 percent / benzene / 48 h / Heating
2: DIBAL-H / diethyl ether; hexane / 1 h / 0 °C
3: MnO2 / CHCl3 / 72 h / 20 °C
4: 54 percent / benzene / 48 h / Heating
5: DIBAL-H / diethyl ether; hexane / 1 h / 0 °C
6: MnO2 / CHCl3 / 72 h / 20 °C
7: 80 percent / benzene / 48 h / Heating
8: DIBAL-H / diethyl ether; hexane / 1 h / 0 °C
View Scheme
参考文献
Venkataraman; Hemalatha; Cha, Jin K.
Tetrahedron Letters, 1987 , vol. 28, # 22 p. 2455 - 2458
反应条件
1.1: t-butyllithium / tetrahydrofuran; pentane / -78 - 0 °C
1.2: 92 percent / tetrahydrofuran; pentane / -78 - 0 °C
2.1: 70 percent / Dess-Martin periodinane; pyridine / CH2Cl2 / 23 °C
View Scheme
参考文献
Liang, Guangxin; Gradl, Stefan N.; Trauner, Dirk
Organic Letters, 2003 , vol. 5, # 26 p. 4931 - 4934
参考文献
I.G.Farbenind.
Patent: DE739438 , 1938 ;
DRP/DRBP Org.Chem.
Full Text Show Details
Eastman Kodak Co.
Patent: US2432394 , 1946 ;
反应条件
in tetrahydrofuran
T=20°C; 1.66667 h; Molecular sieve;
参考文献
Calow, Adam D. J.; Batsanov, Andrei S.; Fernandez, Elena; Sole, Cristina; Whiting, Andrew
Chemical Communications, 2012 , vol. 48, # 93 p. 11401 - 11403
