in melt byproducts: NaF, CO2; Electrolysis; add. of Na2CO3 results in a formation of Al2O3 via side reaction (2 AlF3 + 3 Na2CO3 = Al2O3 + 6 NaF + 3 CO2);;
in melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detd. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
参考文献
Wartena, Ryan; Winnick, Jack; Pfromm, Peter H.
Journal of the Electrochemical Society, 2002 , vol. 149, # 9 p. D125-D131
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反应条件
in melt Kinetics; byproducts: O2, CO; Electrolysis; solid, granular sodium salts placed in alumina crucible and tube, purgedwith argon for 3 h, heated at 840.+-.20°C; detn. by IR gas analyzer, electrochemical cell analyzer, capillary ion electrophoresis, inductively coupled plasma anal., acid titration;
参考文献
Wartena, Ryan; Winnick, Jack; Pfromm, Peter H.
Journal of the Electrochemical Society, 2002 , vol. 149, # 9 p. D125-D131
