hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III); 3-chloro-benzenecarboperoxoic acid in dichloromethane T=-78°C; 3 h; competitive epoxidation in the presence of var. iron porphyrins; other alkenes, other oxidants, other catalyst, other solvents;
参考文献
Machii, Kenji; Watanabe, Yoshihito; Morishima, Isao
Journal of the American Chemical Society, 1995 , vol. 117, # 25 p. 6691 - 6697
UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS; CLARKE, Matthew Lee; KONRAD, Tina Maria
Patent: WO2011/30110 A2, 2011 ;
Location in patent: Page/Page column 30-31 ;
1.1: ethyl acetate / 0 - 25 °C / Industry scale 1.2: 0 - 25 °C / Industry scale 1.3: 0 - 15 °C / pH 7 / Industry scale 2.1: hydrogenchloride / water / 12 h / 25 °C 3.1: thionyl chloride / 0 °C / Reflux View Scheme
参考文献
ANADYS PHARMACEUTICALS, INC.
Patent: WO2008/124450 A1, 2008 ;
