magnesium in diethyl ether 1.) reflux, 4.5 h, 2.) -60 - -45 deg C, 1 h; room temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Duncan, James A.; Bohle, D. Scott; Blanchard, Charles A.; Bosse, Mark L.; Noland, Terry W.; et al.
Journal of the American Chemical Society, 1982 , vol. 104, # 10 p. 2837 - 2839
1.4-(CH3O2C)2C6H4Cr(CO)3; hydrogen in cyclohexane T=170°C; P=31028.9 Torr; 30 h; var. ligands in complexes of methyl benzoate Cr(CO)2L, var. reaction times; Product distribution;
Parahydrogen (about; lt;Rh(2,5-norbornadiene)(PPh3)gt;*PF6 in acetone Ambient temperature; Mechanism;
参考文献
Hermans, Sophie; Raja, Robert; Thomas, John M.; Johnson, Brian F. G.; Sankar, Gopinathan; Gleeson, David
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1211 - 1215
