N-(4-溴苯基)-N,N-双(1,1-联苯-4-基)胺合成路线 （共 11 条）
反应条件
sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine in toluene
T=90°C; 3 h;
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292603 A1, 2011 ;
Location in patent: Page/Page column 25 ;
反应条件
N-bromosuccinmide in ethyl acetate; toluene
T=20°C; 120 h;
参考文献
SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Patent: WO2009/72587 A1, 2009 ;
Location in patent: Page/Page column 152-153 ;
反应条件
sodium t-butanolate; bis-triphenylphosphine-palladium(II) chloride in xylene
T=130°C; 24 h;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1584614 A1, 2005 ;
Location in patent: Page/Page column 20 ;
反应条件
1,10-phenanthroline; potassium carbonate; copper(l) iodide in xylene
24 h; Reflux;
参考文献
LG Chem, Ltd.
Patent: EP2311826 A2, 2011 ;
Location in patent: Page/Page column 72 ;
反应条件
tris-(dibenzylideneacetone)dipalladium(0) in toluene
参考文献
DOOSAN CORPORATION
Patent: US2012/168730 A1, 2012 ;
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran; water; toluene
T=80°C; Suzuki coupling; 8 h;
参考文献
Cho, Joong Hyun; Ryu, Young-Sil; Oh, Se Hwan; Kwon, Jae Kwan; Yum, Eul Kgun
Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 7 p. 2461 - 2464
反应条件
1: sodium t-butanolate / tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 3 h / 90 °C
2: sodium t-butanolate / tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 3 h / 90 °C
View Scheme
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292603 A1, 2011 ;
反应条件
1: sodium t-butanolate / tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 3 h / 90 °C
2: sodium t-butanolate / tri-tert-butyl phosphine; tris-(dibenzylideneacetone)dipalladium(0) / toluene / 3 h / 90 °C
View Scheme
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292603 A1, 2011 ;
反应条件
1: bromine / chloroform / 2 h / 0 °C
2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water; toluene / 8 h / 80 °C
View Scheme
参考文献
Cho, Joong Hyun; Ryu, Young-Sil; Oh, Se Hwan; Kwon, Jae Kwan; Yum, Eul Kgun
Bulletin of the Korean Chemical Society, 2011 , vol. 32, # 7 p. 2461 - 2464
反应条件
1: N-bromosuccinmide / N,N-dimethyl-formamide / 0 - 20 °C
2: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / |Inert atmosphere; |Reflux
3: palladium diacetate; triphenylphosphine; sodium t-butanolate / toluene / |Inert atmosphere; |Reflux
View Scheme
参考文献
Universal Display Corporation; Kwong, Raymond; Lam, Siu Tung; Lee, Chi Hang; Lam, Sze Kui
Patent: US2013/241401 A1, 2013 ;
