1: acetonitrile / 1 h / 75 °C / Large scale reaction 2: hydrogen; sodium hydrogencarbonate / methanol / 2.5 h / 35 - 40 °C / 6750.68 Torr / Large scale reaction 3: methanol; sodium methylate / 1 h / 44 °C / 760.05 Torr / Large scale reaction View Scheme
参考文献
Gordon, Gregory E. R.; Bode, Moira L.; Visser, Daniel F.; Lepuru, M. Jerry; Zeevaart, Jacob G.; Ragubeer, Nasheen; Ratsaka, Molala; Brady, Dean; Walwyn, David R.
Organic Process Research and Development, 2011 , vol. 15, # 1 p. 258 - 265
copper(II) sulfate; ascorbic acid powder in water 0.0833333 h; Ambient temperature;
参考文献
Yanada, Reiko; Akiyama, Taishin; Harayama, Takashi; Yanada, Kazuo; Meguri Haruo; Yoneda, Fumio
Journal of the Chemical Society, Chemical Communications, 1989 , p. 238 - 239
in methanol; water Irradiationother solvent (dioxane); photolysis; photolability; half-lifes of the photocleavage reaction; solvent effect; proposed mechanism of photocleavage of 2-(2-nitrophenyl)ethoxycarbonyl protecting groups; Product distribution;