[Pd2Cl2(μ-Cl)2((S)-μ-3,5-xyl-phanephos)]; water; toluene-4-sulfonic acid; lithium chloride in butanone T=50°C; P=22502.3 Torr; 42 h; Autoclave; optical yield given as percent eeenantioselective reaction;
参考文献
Konrad, Tina M.; Fuentes, Jose A.; Slawin, Alexandra M. Z.; Clarke, Matthew L.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 48 p. 9197 - 9200
1: With trimethylsilyl cyanide; 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile T=25°C; 2 h; 2: With hydrogenchloride in diethyl ether; water T=20°C; 3 h;
1: With bis(acetylacetonate)nickel(II); tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether T=20°C; P=760.051 Torr; 3 h; 2: With hydrogenchloride; water in ethylene glycol dimethyl ether
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide T=110°C; Heck reaction; 20 h; 2: With sodium hydroxide; water in N,N-dimethyl-formamide T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
