反应条件
Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '9361534', constants.ctx, '0')">(1R,4S,5R)-[2-bromo-3-(3,4-dimethoxybenzyloxymethyl)-4,5-dimethyl-4-vinyl-cyclohex-2-enyloxy]-tert-butyldimethylsilane</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '3587204', constants.ctx, '0')">tert.-butyl lithium</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '1696894', constants.ctx, '0')">diethyl ether</a>; <a href="#" onclick="return RXDsubstances(event, this, '969132', constants.ctx, '0')">pentane</a> <br />T=-78°C; 0.5 h; <br />Stage #2: <a href="#" onclick="return RXDsubstances(event, this, '9324994', constants.ctx, '0')">(2S,3R,6E)-3-(4-iodopent-3-enyl)-3-methyl-oxirane-2-carbaldehyde</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '1732991', constants.ctx, '0')">N,N,N',N,-tetramethylethylenediamine</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '1696894', constants.ctx, '0')">diethyl ether</a>; <a href="#" onclick="return RXDsubstances(event, this, '969132', constants.ctx, '0')">pentane</a> <br />T=-78°C; 0.0833333 h; Further stages.; <br />
参考文献
Mohr, Peter J.; Halcomb, Randall L. Journal of the American Chemical Society, 2003 , vol. 125, # 7 p. 1712 - 1713
