2-(1-苯并噻吩-5-基)-4,4,5,5-四甲基-1,3,2-二氧硼烷合成路线 (共 2 条)
反应条件
potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in dimethyl sulfoxide T=20 - 80°C; 3 h;
参考文献
WO2004/9086 A1, ;
Page/Page column 49 ;
WO 2004/009086 A1
反应条件
1: With boron trichloride in dichloromethane
T=-78 - 20°C; 0.25 h;
2: With methanol in dichloromethane
T=20°C;
参考文献
Herold, Peter; Mah, Robert; Tschinke, Vincenzo; Behnke, Dirk; Marti, Christiane; Jotterand, Nathalie; Stutz, Stefan; Quirmbach, Michael
Patent: US2009/306064 A1, 2009 ;
Location in patent: Page/Page column 55 ;
US 20090306064 A1