1-氯-3-甲基-2-丁烯合成路线 （共 287 条）
反应条件
sodium 1.) ether, 1 h, 2.) ether, reflux, 30 min; Yield given. Multistep reaction;
参考文献
Yamada, Shigetoshi; Takeshita, Toru; Tanaka, Juntaro
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 9 p. 2901 - 2902
反应条件
copper(l) iodide; magnesium Multistep reaction;
参考文献
Rathore, Rajendra; Vankar, Padma S.; Chandrasekaran, S.
Tetrahedron Letters, 1986 , vol. 27, # 34 p. 4079 - 4082
反应条件
copper(l) iodide; potassium carbonate; sodium sulfite; 1,8-diazabicyclo[5.4.0]undec-7-ene in dimethyl sulfoxide T=30°C; 4 h;
参考文献
Bieber, Lothar W.; da Silva, Margarete F.
Tetrahedron Letters, 2007 , vol. 48, # 40 p. 7088 - 7090
反应条件
copper(l) iodide; potassium carbonate in N,N-dimethyl-formamide T=40°C; 1.3 h;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, # 7 p. 1445 - 1448
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 7 p. 1565 - 1569
反应条件
bis(acetylacetonate)nickel(II); diisobutylaluminium hydride; triphenylphosphine in tetrahydrofuran; toluene 20 h; Heating; Yield given. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 60, # 18 p. 5752 - 5756
反应条件
copper(l) iodide; potassium carbonate in N,N-dimethyl-formamide 3 h;
参考文献
Russian Journal of Organic Chemistry, , vol. 36, # 11 p. 1572 - 1576
反应条件
in diethyl ether 72 h;
参考文献
Journal of Organic Chemistry, , vol. 45, # 1 p. 80 - 89
反应条件
1: 2-phenyl-2-(trimethylsilyloxy)ethanenitrile With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=-78°C; 1 h; Inert atmosphere;
2: 1-chloro-3-methyl-2-butene in tetrahydrofuran; hexane
T=-78 - 20°C; 5 h; Inert atmosphere;
参考文献
Arpin, Patrice; Hill, Bryan; Larouche-Gauthier, Robin; Spino, Claude
Canadian Journal of Chemistry, 2013 , vol. 91, # 12 p. 1193 - 1201
反应条件
naphthalene; lithium; lithium bromide
1.) THF, -100 deg C, 2.) THF, -100 deg C, 15 min; Yield given. Multistep reaction;
参考文献
Stack, Douglas E.; Dawson, Bryan T.; Rieke, Reuben D.
Journal of the American Chemical Society, 1991 , vol. 113, # 12 p. 4672 - 4673
反应条件
hydrogenchloride; potassium carbonate in tetrahydrofuran; hexane; nitrogen
参考文献
Tsumura and Co.
Patent: US5106871 A1, 1992 ;
