1-氯-3-甲基-2-丁烯合成路线 （共 287 条）
反应条件
bis(acetylacetonate)nickel(II)
T=90°C; 8 h;
参考文献
Marquet, J.; Moreno-Manas, M.
Chemistry Letters, 1981 , p. 173 - 176
反应条件
1: 2-methylpropanoic acid methyl ester With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=0 - 20°C; 0.5 h; Inert atmosphere;
2: 1-chloro-3-methyl-2-butene in tetrahydrofuran; hexane
T=0 - 20°C; 24 h;
参考文献
Takenaka, Kazuhiro; Akita, Mitsutoshi; Tanigaki, Yugo; Takizawa, Shinobu; Sasai, Hiroaki
Organic Letters, 2011 , vol. 13, # 13 p. 3506 - 3509
反应条件
1: (i) NaH, (ii) /BRN= 878156/
2: BF3-Et2O
3: aq. NaOH
View Scheme
参考文献
Dilbeck; Field; Gallo; Gargiulo
Journal of Organic Chemistry, 1978 , vol. 43, # 24 p. 4593 - 4596
反应条件
1: (i) NaH, (ii) /BRN= 878156/
2: BF3-Et2O
View Scheme
参考文献
Dilbeck; Field; Gallo; Gargiulo
Journal of Organic Chemistry, 1978 , vol. 43, # 24 p. 4593 - 4596
反应条件
palladium diacetate; potassium carbonate
T=20°C; P=760 Torr; 1 h;
参考文献
Kiji, Jitsuo; Okano, Tamon; Higashimae, Yukiko; Fukui, Yasuyuki
Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 4 p. 1029 - 1031
反应条件
(i) Mg, (ii) HSiCl3, (iii) /BRN= 3587200/; Multistep reaction;
参考文献
Hosomi,A.; Sakurai,H.
Tetrahedron Letters, 1978 , p. 2589 - 2592
反应条件
potassium tert-butylate
参考文献
Shibuya; Abe; Nakahashi; Kubota
Chemical and Pharmaceutical Bulletin, 1978 , vol. 26, # 9 p. 2671 - 2673
反应条件
zinc(II) chloride in diethyl ether; dichloromethane
T=-78°C;
参考文献
Klein, Herbert; Erbe, Anne; Mayr, Herbert
Angewandte Chemie, 1982 , vol. 94, # 1 p. 63
反应条件
zinc(II) chloride in diethyl ether; dichloromethane
T=-78°C;
参考文献
Klein, Herbert; Erbe, Anne; Mayr, Herbert
Angewandte Chemie, 1982 , vol. 94, # 1 p. 63
反应条件
1: 70 percent / Mg / tetrahydrofuran / Ambient temperature
2: 66 percent Spectr. / singlet O2 / methanol / 0.5 h / 40 °C / Irradiation
View Scheme
参考文献
Dubac, J.; Laporterie, A.; Iloughmane, H.; Pillot, J. P.; Deleris, G.; Dunogues, J.
Journal of Organometallic Chemistry, 1985 , vol. 281, p. 149 - 162
