4-氟-反-beta-苯乙烯硼酸频哪醇酯合成路线 （共 8 条）
反应条件
water in tetrahydrofuran
T=20°C; 12 h; Inert atmosphere;
参考文献
Peng, Ai-Yun; Chen, Ba-Tian; Chen, Pei-Jiang
Journal of Fluorine Chemistry, 2013 , vol. 151, p. 58 - 62
反应条件
sodium methylate; copper in ethanol
T=25°C; 24 h; Schlenk techniqueInert atmosphereSealed tube; regioselective reaction;
参考文献
Zhao, Jie; Niu, Zhiqiang; Fu, Hua; Li, Yadong
Chemical Communications, 2014 , vol. 50, # 16 p. 2058 - 2060
反应条件
NaOC(CH3)3; CH3OH; [(N,N′-bis[2,6-diisopropylphenyl]imidazolin-2-ylidene)CuCl] in tetrahydrofuran
1.0 molpercent Cu-complex, alkyne, diborane, NaOC(CH3)3, CH3OH, THF, -15°C, 24 h, N2 atm.; 87:13 ratio of isomers;
参考文献
Jang, Hwanjong; Zhugralin, Adil R.; Lee, Yunmi; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7859 - 7871
反应条件
2Fe(1+)*9CO in toluene
T=100°C; 24 h; Inert atmosphere;
参考文献
Haberberger, Michael; Enthaler, Stephan
Chemistry - An Asian Journal, 2013 , vol. 8, # 1 p. 50 - 54
反应条件
Ω-SIMes-CF3 in toluene
1 h; Inert atmosphereReflux; stereoselective reaction;
参考文献
Hemelaere, Remy; Caijo, Frederic; Mauduit, Marc; Carreaux, Francois; Carboni, Bertrand
European Journal of Organic Chemistry, 2014 , vol. 2014, # 16 p. 3328 - 3333
反应条件
Rh(acetylacetonato)(.kappa.2-2,6-diisopropyl-N-((pyridin-2-yl)methylene)benzenamine) in benzene-d6
B compd. in C6D6 added to a soln. of Rh complex and CH3OC6H4CHCH2, reacted at room temp. for 18 h; not isolated, detected by NMR, MS;
参考文献
Kanas, Diane A.; Geier, Stephen J.; Vogels, Christopher M.; Decken, Andreas; Westcott, Stephen A.
Inorganic Chemistry, 2008 , vol. 47, # 19 p. 8727 - 8735
反应条件
1: 0 - 70 °C / |Inert atmosphere
2: water / tetrahydrofuran / 12 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Peng, Ai-Yun; Chen, Ba-Tian; Chen, Pei-Jiang
Journal of Fluorine Chemistry, 2013 , vol. 151, p. 58 - 62
反应条件
rhodium complex bound to sila-bond diphenylphosphine in tetrahydrofuran
18 h;
参考文献
Geier, Michael J.; Geier, Stephen J.; Vogels, Christopher M.; Beland, Francois; Westcott, Stephen A.
Synlett, 2009 , # 3 p. 477 - 481
