3-甲基-1,5-庚二烯合成路线 （共 11 条）
反应条件
bis(cyclopentadienyl)titanium dichloride; manganese in tetrahydrofuran
T=20°C;
参考文献
Barrero, Alejandro F.; Herrador, M. Mar; Quilez Del Moral, Jose F.; Arteaga, Pilar; Arteaga, Jesus F.; Dieguez, Horacio R.; Sanchez, Elena M.
Journal of Organic Chemistry, 2007 , vol. 72, # 8 p. 2988 - 2995
反应条件
maleic anhydride
1.) ether, -30 deg C, 2 h; 2.) ether, THF, -30 deg C, 2 h, -30 deg C to RT; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Goliaszewski, Alan; Schwartz, Jeffrey
Journal of the American Chemical Society, 1984 , vol. 106, # 17 p. 5028 - 5030
反应条件
magnesium in diethyl ether
Heating; Further byproducts given;
参考文献
Pasto, Daniel J.; L'Hermine, Gael
Tetrahedron, 1993 , vol. 49, # 16 p. 3259 - 3272
反应条件
magnesium in diethyl ether
Heating; Further byproducts given;
参考文献
Pasto, Daniel J.; L'Hermine, Gael
Tetrahedron, 1993 , vol. 49, # 16 p. 3259 - 3272
反应条件
tri-n-butylborane in diethyl ether
regioselectivity; other reagents; Product distribution;
参考文献
Yamamoto, Yoshinori; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 1969 - 1975
反应条件
tri-n-butylborane in diethyl ether
regioselectivity; Product distribution;
参考文献
Yamamoto, Yoshinori; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 1969 - 1975
反应条件
hydrogenchloride; iso-propylmagnesium bromide
1) ether, 5 h, 2) 0 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Lehmkuhl, Herbert; Fustero, Santos
Liebigs Annalen der Chemie, 1980 , # 9 p. 1353 - 1360
反应条件
in diethyl ether
regioselectivity; Product distribution;
参考文献
Yamamoto, Yoshinori; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 1969 - 1975
反应条件
in diethyl ether
regioselectivity; Product distribution;
参考文献
Yamamoto, Yoshinori; Yatagai, Hidetaka; Maruyama, Kazuhiro
Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 1969 - 1975
反应条件
Yield given. Multistep reaction;
参考文献
Goliaszewski, Alan; Schwartz, Jeffrey
Tetrahedron, 1985 , vol. 41, # 24 p. 5779 - 5790
